Slurry catalyst and slurry flakes valorization
The instant invention discloses a method for the valorization of spent catalyst from hydrocarbon processing slurry reactors as well as slurry flakes.
1. A method for recycling molybdenum, vanadium and nickel contained in a spent catalyst and/or a metal containing hydrocarbon feedstock, wherein said spent catalyst and/or metal containing hydrocarbon feedstock successively undergoes (i) calcination performed so as to collect carbon monoxide and hydrogen and to remove carbon containing material, (ii) washing with water, (iii) acidification with sulfuric acid to obtain an acidic water and a first precipitate which is separated, (iv) alkalinization of said acidic water with sodium hydroxide to obtain an alkaline water and a second precipitate which is separated, wherein said spent catalyst and/or metal containing hydrocarbon feedstock is obtained by the treatment of a metal containing hydrocarbon feedstock issued from an industrial unit using a metal containing catalyst, and wherein before step (i) said spent catalyst and/or metal containing hydrocarbon feedstock are collected and treated to produce carbon monoxide, hydrogen and a metal containing residue, said metal containing residue being processed by steps (i) to (iv).
2. A method according to claim 1 , wherein iron chlorosulfate (FeCl(SO 4 )) is added at steps (iii) and (iv).
3. A method according to claim 1 , wherein (v) said alkaline water is further neutralized with an acid.
4. A method according to claim 1 , wherein first and/or second precipitate is introduced into melted iron to obtain vanadium pentoxide (V 2 O 5 ), and iron-molybdenum-nickel alloy.
5. A method according to claim 1 , wherein the treatment of said spent catalyst and/or metal containing hydrocarbon feedstock before step (i) is a calcination.
6. A method according to claim 5 , wherein the treatment is a calcination under partial oxidation conditions.
7. A method according to claim 1 , wherein the industrial unit is a slurry plant.
8. A method according to claim 1 , wherein the metal containing hydrocarbon feedstock is issued from a reactor of an industrial unit.
9. A method according to claim 1 , wherein the metal contained in the metal containing catalyst or in the spent metal containing catalyst and the metal contained in the metal containing hydrocarbon feedstock or in the metal containing residual hydrocarbon feedstock are each independently selected among aluminum, tin, transition metals and combinations thereof.
10. A method according to claim 9 , wherein the metal contained in the metal containing catalyst or in the spent metal containing catalyst is selected among aluminum, iron, molybdenum, tungsten, nickel, cobalt and their combinations.
11. A method according to claim 9 , wherein the metal contained in the metal containing hydrocarbon feedstock or in the metal containing residual hydrocarbon feedstock is selected among vanadium, nickel, cobalt, iron, and combinations thereof.
12. A method according to claim 1 , wherein hydrogen is used for the hydroconversion of the metal containing hydrocarbon feedstock.
13. A method according to claim 1 , wherein the metal containing residue is recycled to produce fresh metal containing catalyst.
14. A method according to claim 1 , further comprising hydroconversion of a hydrocarbon feedstock in a slurry reactor, using said hydrogen.
15. A method according to claim 7 , wherein said spent metal containing catalyst and metal containing residual hydrocarbon feedstock are issued from deasphalting residue.
16. A method for producing hydrogen, comprising recycling a spent catalyst and/or a metal containing hydrocarbon feedstock, by performing the method according to claim 1 , so as to collect hydrogen.