Prevention, actuation and control of deployment of memory-shape polymer foam-based expandables
Actuation and control of the deployment of a polymeric memory-shape material on a wellbore device on a downhole tool may be accomplished by treating a compacted or compressed polymeric memory-shape material with an optional deployment fluid to lower its T g and/or decrease its rigidity, thereby softening the polymeric shape-memory material at a given temperature and triggering its expansion or recovery at a lower temperature. Recovering the polymeric shape-memory material may occur by its being exposed to a particular temperature range. Alternatively, the deployment of the compacted or compressed polymeric memory-shape material may be prevented or inhibited by shielding the material with an environment of a fluid that does not substantially lower its T g , decrease its rigidity or both, and then subsequently contacting the material with a deployment fluid. The deployment fluid may be removed during the method.
1. A method of installing a wellbore device on a downhole tool in a wellbore, the method comprising:
introducing the downhole tool bearing the wellbore device into a wellbore, where the wellbore device comprises at least one polymeric shape-memory material having an original glass transition temperature (T g ) and an original rigidity, where the polymeric shape-memory material is in an altered geometric position and the polymeric shape-memory material is contacted by a first fluid;
substantially removing the first fluid;
contacting the polymeric shape-memory material with a deployment fluid in an amount effective to have an effect upon the polymeric shape-memory material, the effect selected from the group consisting of lowering the T g , decreasing the rigidity, and both;
removing the deployment fluid; and
recovering the polymeric shape-memory material from its altered geometric position for run-in to a recovered geometric position;
where the wellbore device has the property that when substantially all of the deployment fluid is removed from the polymeric shape-memory material, an effect is obtained selected from the group consisting of restoring the T g to within at least about 90% of the original T g , restoring the rigidity within at least about 25% of the original rigidity, and both.
2. The method of claim 1 further comprising expanding the polymeric shape-memory material from its altered geometric position to a recovered geometric position.
3. The method of claim 1 where the polymeric shape-memory material is selected from the group consisting of polyurethanes, polyurethanes made by reacting a polycarbonate polyol with a polyisocyanate, polyamides, polyureas, polyvinyl alcohols, vinyl alcohol-vinyl ester copolymers, phenolic polymers, polybenzimidazoles, polyethylene oxide/acrylic acid/methacrylic acid copolymer crosslinked with N,N′-methylene-bis-acrylamide, polyethylene oxide/methacrylic acid/N-vinyl-2-pyrrolidone copolymer crosslinked with ethylene glycol dimethacrylate, polyethylene oxide/poly(methyl methacrylate)/N-vinyl-2-pyrrolidone copolymer crosslinked with ethylene glycol dimethacrylate, and combinations thereof.
4. The method of claim 1 where the polymeric shape-memory material is a polyurethane formed by a process comprising reacting a polycarbonate polyol with an isocyanate.
5. The method of claim 1 where the first fluid is a hydrocarbon-based fluid and where the deployment fluid is selected from the group consisting of water, brines, dimethyl sulfoxide, ketones, alcohols, glycols, ethers, and mixtures thereof.
6. The method of claim 1 where the wellbore device is selected from the group consisting of an expansion tool, a screen, a packer, an isolation plug and combinations thereof.
7. A method of installing a wellbore device on a downhole tool in a wellbore, the method comprising:
introducing the downhole tool bearing the wellbore device into a wellbore, where the wellbore device comprises:
a substrate; and
at least one polymeric shape-memory material on the substrate, the polymeric shape-memory material having an original glass transition temperature (T g ) and an original rigidity, where the polymeric shape-memory material is in an altered geometric position and the polymeric shape-memory material is contacted by a first fluid, where the polymeric shape-memory material is selected from the group consisting of polyurethanes, polyurethanes made by reacting a polycarbonate polyol with a polyisocyanate, polyamides, polyureas, polyvinyl alcohols, vinyl alcohol-vinyl ester copolymers, phenolic polymers, polybenzimidazoles, polyethylene oxide/acrylic acid/methacrylic acid copolymer crosslinked with N,N′-methylene-bis-acrylamide, polyethylene oxide/methacrylic acid/N-vinyl-2-pyrrolidone copolymer crosslinked with ethylene glycol dimethacrylate, polyethylene oxide/poly(methyl methacrylate)/N-vinyl-2-pyrrolidone copolymer crosslinked with ethylene glycol dimethacrylate, and combinations thereof;
substantially removing the first fluid;
contacting the polymeric shape-memory material with a deployment fluid in an amount effective to have an effect upon the polymeric shape-memory material, the effect selected from the group consisting of lowering the T g resulting in a second and lower T g , decreasing the original rigidity resulting in a second, decreased rigidity, and both;
removing the deployment fluid; and
recovering the polymeric shape-memory material from its altered geometric position for run-in to a recovered geometric position,
where the wellbore device has the property that when substantially all of the deployment fluid is removed from the polymeric shape-memory material, an effect is obtained selected from the group consisting of restoring the T g to within at least about 90% of the original T g , restoring the rigidity within at least about 25% of the original rigidity, and both.
8. The method of claim 7 where the polymeric shape-memory material is a polyurethane formed by a process comprising reacting a polycarbonate polyol with an isocyanate.
9. The method of claim 7 where the first fluid is a hydrocarbon-based fluid and where the deployment fluid is selected from the group consisting of water, brines, dimethyl sulfoxide, ketones, alcohols, glycols, ethers, and mixtures thereof.
10. The method of claim 7 where the wellbore device is selected from the group consisting of an expansion tool, a screen, a packer, an isolation plug and combinations thereof.