Iridium alloy excellent in hardness, workability and anti-contamination properties
The present invention provides an iridium alloy suitable for a wire rod for probe pins, with zirconium as an additive element contained as an essential element and with aluminum and/or copper further added. In this iridium alloy, the additive concentration of zirconium is 100 to 500 ppm and the total additive concentration of aluminum and copper is 10 to 500 ppm. The present invention will be able to meet such requirements placed on a material for probe pins as that further miniaturization thereof would be demanded in the future and that use environment thereof becomes severe.
1. An iridium alloy suitable for a wire rod for probe pins, said alloy consisting of zirconium as an additive element, aluminum and/or copper as a further additive element, and the balance iridium, wherein the additive element concentration of zirconium is 100 to 500 ppm, and the total additive element concentration of aluminum and/or copper is 10 to 500 ppm.
2. The iridium alloy according to claim 1 , wherein the total concentration of additive elements is not more than 600 ppm.
3. A probe pin consisting of an iridium alloy, said alloy consisting of zirconium as an additive element, aluminum and/or copper as a further additive element, and the balance iridium, wherein the additive element concentration of zirconium is 100 to 500 ppm, and the total additive element concentration of aluminum and/or copper is 10 to 500 ppm.
4. A probe pin according to claim 3 , wherein the total concentration of additive elements is not more than 600 ppm.
5. A probe pin according to claim 3 , having a surface hardness of at least 600 Hv.
6. A probe pin according to claim 5 , having a surface hardness of at least 700 Hv.
7. A manufacturing method of a wire rod for probe pins, comprising the steps of:
(a) casting an alloy consisting of zirconium as an additive element, aluminum and/or copper as a further additive element, and the balance iridium, and making a bar by casting the alloy;
(b) forming a wire rod having a wire diameter of 0.5 to 1.0 mm by hot working the bar;
(c) subjecting the wire rod, at least once, to a combination of annealing at 1000 to 1200° C. and wire drawing of not less than one pass under heat by electric current application; and
(d) subjecting the wire rod after wire drawing under heat by electric current application, at least once, to a combination of annealing at 900 to 1200° C. and cold wire drawing of not less than one pass.
8. The manufacturing method according to claim 7 wherein the additive element concentration of zirconium is 100 to 500 ppm, and the total additive element concentration of aluminum and/or copper is 10 to 500 ppm.
9. The manufacturing method according to claim 8 wherein the total concentration of additive elements is not more than 600 ppm.