Method of controlling aspect ratio of nano-structure, method of producing nano-structure using the same and nano-structure produced thereby
Provided are a method of easily controlling the aspect ratio of a nano-structure, which can be effectively used in various fields of application, including a positive active material for a rechargeable battery, an electrode material for a storage battery, a redox catalyst, a molecule support, and so on, and by which various nano-structures of desired sizes can be easily produced according to the necessity. The method includes preparing a mixed solution including a manganese salt and an oxidant, adding a pH controlling additive to the mixed solution and controlling a pH level of the mixed solution using the following equation, and heating the pH-controlled mixed solution at a temperature in a range of 50□ to 200□ for 1 hour to 10 days to cause a reaction to take place: Specific surface area (m 2 /g)=0.2 pH 2 +2.
1. A method of controlling the aspect ratio of a nano-structure, the method comprising:
preparing a mixed solution including a manganese salt and an oxidant;
adding a pH controlling additive to the mixed solution and controlling a pH level of the mixed solution using the following equation; and
heating the pH-controlled mixed solution at a temperature in a range of 50° C. to 200° C. for 1 hour to 10 days to cause a reaction to take place:
Specific surface area (m 2 /g)=0.2 pH 2 +2.
2. The method of claim 1 , wherein the manganese salt is at least one metal salt selected from the group consisting of MnSO 4 , Mn(NO 3 ) 2 , MnCl 2 , Mn(CH 3 COO) 2 and hydrates thereof.
3. The method of claim 1 , wherein the oxidant is at least one compound selected from the group consisting of (NH 4 ) 2 S 2 O 8 , Li 2 S 2 O 8 , Na 2 S 2 O 8 , and K 2 S 2 O 8 .
4. The method of claim 1 , wherein the pH controlling additive is at least one compound selected from the group consisting of H 2 SO 4 , HNO 3 , HCl, CH 3 COOH, LiOH, NaOH, and KOH.
5. The method of claim 1 , wherein 100 to 500 parts by weight of the oxidant is added based on 100 parts by weight of the manganese salt.
6. A method of producing a nano-structure, the aspect ratio of which is controlled by the method claimed in any one of claims 1 to 5 .
7. A method of producing a lithium manganese oxide nano-structure, the method comprising:
producing a manganese oxide nano-structure, the aspect ratio of which is controlled by the method claimed in any one of claims 1 to 5 ;
mixing the manganese oxide nano-structure and a lithium salt in an organic solvent; and
annealing the mixture at a temperature in a range of 300° C. to 700° C. for 1 hour to 10 days.
8. The method of claim 7 , wherein the lithium salt is at least one selected from the group consisting of LiOH, LiNO 3 , Li 2 CO 3 , Li(CH 3 O), Li(CH 3 CH 2 O), Li(CH 3 COO), Li 2 O and hydrates thereof.
9. The method of claim 7 , wherein 10 to 200 parts by weight of the lithium salt is added based on 100 parts by weight of the manganese oxide nano-structure.