Silica aerogels and their preparation
Silica aerogels with improved properties are disclosed together with methods for synthesizing such aerogels. The improved properties include lower thermal conductivity (better insulating capacity), lower acoustic velocity, lower dielectric constant and improved ductility. Greater tunability of the refractive index can also be achieved. The silica aerogels are prepared by a sol-gel processing method that provides better control of the formation of aerogel structures. Generally speaking, the improvements arise from control of the synthesis to create a morphology of primary clusters and diverse-sized secondary clusters of dense silica aerogels separated by less densely packed regions. By providing a broader range of secondary clusters and/or pore sizes and loose connectivity between clusters, reductions can be achieved in thermal conductivity and flexural modulus.
1. A silica aerogel, free of a non-silica content, comprising:
a network of primary silicate clusters comprising silica particles having diameters from 1 to 10 nm interconnected to form diversely-sized secondary silicate clusters having diameters greater than 20 nm,
a porosity of greater than about 80 percent,
a diverse range of pore sizes with pores of less than 5 nm in size and pores greater than 50 nm in size, wherein the range of pore sizes exhibits a distribution curve having full-width-half-max range of at least 30 nm,
a bulk density between about 0.08 g/cm 3 and about 0.12 g/cm 3 ,
a surface area greater than about 800 m 2 /g,
a flexural modulus less than about 1×10 6 Pascal, and
a thermal conductivity less than about 14 mW/mK at one atmosphere of pressure.
2. The silica aerogel of claim 1 wherein the diverse range of pore sizes includes pores of less than 3 nm in size and pores greater than 70 nm in size.
3. The silica aerogel of claim 1 wherein the aerogel exhibits a thermal conductivity of less than about 10 mW/mK at one atmosphere of pressure.
4. The silica aerogel of claim 1 wherein the aerogel exhibits a thermal conductivity of less than about 4 mW/mK at 0.1 atmospheres of pressure.
5. The silica aerogel of claim 1 wherein the aerogel exhibits an aerogel bulk density between about 0.08 g/cm 3 and about 0.1 g/cm 3 .
6. The silica aerogel of claim 1 wherein the aerogel exhibits a porosity of greater than about 90 percent, and a surface area greater than about 1000 m 2 /g.
7. A silica aerogel, free of a non-silica content, comprising:
a network of primary silicate clusters comprising silica particles having diameters from 1 to 10 nm interconnected to form diversely-sized secondary silicate clusters having diameters greater than 20 nm,
a porosity of greater than about 80 percent,
a diverse range of pore sizes with pores of less than 5 nm in size and pores greater than 50 nm in size, wherein the aerogel exhibits an average pore size between about 10 nm and about 30 nm and a distribution of pore sizes that spans at least 50 nm,
a bulk density between about 0.08 g/cm 3 and about 0.12 g/cm 3 ,
a surface area greater than about 800 m 2 /g,
a flexural modulus less than about 1×10 6 Pascal, and
a thermal conductivity less than about 14 mW/mK at one atmosphere of pressure.
8. The silica aerogel of claim 7 wherein the aerogel exhibits a thermal conductivity of less than about 10 mW/mK at one atmosphere of pressure.
9. The silica aerogel of claim 7 wherein the aerogel exhibits a thermal conductivity of less than about 4 mW/mK at 0.1 atmospheres of pressure.
10. The silica aerogel of claim 7 wherein the aerogel exhibits an aerogel bulk density between about 0.08 g/cm 3 and about 0.1 g/cm 3 .
11. The silica aerogel of claim 7 wherein the aerogel exhibits a porosity of greater than about 90 percent, and a surface area greater than about 1000 m 2 /g.