Zeolite for treatment of nonaqueous electrolytic solution and treatment method of nonaqueous electrolytic solution
An object of the present invention is to provide a zeolite enabling a dehydration treatment of a nonaqueous electrolytic solution without causing a problem of elution of sodium from the zeolite at the time of dehydrating a nonaqueous electrolytic solution for a lithium battery by using a zeolite. The present invention relates to a zeolite, wherein from 97.5 to 99.5 mol % of the ion-exchangeable cation is ion-exchanged with lithium, and when this zeolite is used, a nonaqueous electrolytic solution can be dehydrated while keeping the elution of a cation impurity such as sodium down to 50 ppm or less. As for the zeolite species, at least one or more zeolites selected from the group consisting of A-type, chabazite, ferrierite, ZSM-5 and clinoptilolite can be used.
1. A zeolite shaped body configured for treatment of a nonaqueous electrolytic solution, comprising:
a zeolite for treatment of a nonaqueous electrolytic solution, the zeolite containing an ion-exchangeable cation,
wherein from 97.5 to 99.5 mol % of the ion-exchangeable cation in the zeolite is ion-exchanged with lithium,
the shaped body has a shape that is spherical, cylindrical, trefoil, elliptical or a hollow shape,
the shaped body is from 0.3 to 5 mm in diameter, and
the zeolite is an A-type zeolite having a pore size about 6 Å or less.
2. The zeolite shaped body for treatment of a nonaqueous electrolytic solution as claimed in claim 1 , wherein from 98.0 to 99.0 mol % of the ion-exchangeable cation in the zeolite is ion-exchanged with lithium.
3. The zeolite shaped body for treatment of a nonaqueous electrolytic solution as claimed in claim 1 , obtained by shaping the zeolite for treatment of a nonaqueous electrolytic solution.
4. The zeolite shaped body for treatment of a nonaqueous electrolytic solution as claimed in claim 1 , containing 95 wt % or more of said zeolite for treatment of a nonaqueous electrolytic solution.
5. A production method of a nonaqueous electrolytic solution, comprising: contacting a nonaqueous electrolytic solution-with the zeolite shaped body as described in claim 1 .
6. A lithium battery comprising: the zeolite shaped body for treatment of a nonaqueous electrolytic solution as described in claim 1 ; and a nonaqueous electrolytic solution.