Regenerative purification of a pretreated biomass stream
It is disclosed a process for removing at least a portion of the furfural and acetic acid in a first stream comprised of water, at least one compound selected from the group consisting of furfural and acetic acid, C5's and C6's. Such process comprises the steps of contacting the stream with an adsorption media which has been previously contacted with a second stream comprised of the same components and the adsorption media has been regenerated by exposing it to conditions, without being in contact with the second stream, such that at least 70% of the adsorbed furfural and acetic acid have each been desorbed and at least 60% of the C5's and C6's remain adsorbed on the media.
1. An article of manufacture comprised of
a regenerated adsorption media which has been made by
contacting the adsorption media, which is a high surface polymer, with a liquid stream comprised of water, C5's, C6's, furfural and acetic acid
wherein the C5's are selected from the group consisting of the monomers, dimers, oligomers and polymers of arabinose and xylose,
and the C6's are selected from the group consisting of the monomers, dimers, oligomers and polymers of glucose,
for sufficient time so that the amount of the C5's and the C6's adsorbed onto the media are at least 90% of the maximum level of the C5's and the C6's that can be respectively adsorbed onto the media and the media subsequently regenerated so that the amount of C5's and C6's on the media are at least 76% of the maximum level of the C5's and the C6's that can be respectively adsorbed onto the media, and at least 50% by weight of the total amount of the furfural and acetic acid, respectively is removed from the media.
2. The article of claim 1 , wherein the amount of C5's and C6's on the media is at least 84% of the maximum level of the C5's and the C6's that can be respectively adsorbed onto the media.
3. The article of claim 1 , wherein the amount of C5's and C6's on the media is at least 90% of the maximum level of the C5's and the C6's that can be respectively adsorbed onto the media.
4. The article of claim 1 , wherein the amount of C5's and C6's on the media is at least 95% of the maximum level of the C6's and the C6's that can be respectively adsorbed onto the media.