X-ray intensity correction method and X-ray diffractometer
An X-ray intensity correction method makes the background uniform by adjusting a raster element and an X-ray diffractometer. An X-ray intensity correction method for correcting the intensity of diffracted X-rays includes the steps of focusing X-rays on a sample for correction placed at a gonio center, entering fluorescent X-rays excited by the focused X-rays into a raster element formed by polycapillaries and having a unique focal point, detecting the fluorescent X-rays having passed through the raster element; and adjusting the arrangement of the raster element so that the fluorescent X-rays can uniformly be detected regardless of the detecting position. Since fluorescent X-rays are used, it is possible to adjust the position of the raster element because if the focal point of the raster element coincides with the gonio center, the intensity becomes uniform regardless of the detected position.
1. An X-ray intensity correction method for correcting an intensity of diffracted X-rays by making a background uniform, the method comprising:
focusing X-rays on a sample for correction placed at a gonio center to produce fluorescent X-rays, entering the fluorescent X-rays excited by the X-rays into a raster element being formed by polycapillaries and having a unique focal point, and detecting the fluorescent X-rays having passed through the raster element; and
adjusting an arrangement of the raster element so that the fluorescent X-rays can uniformly be detected regardless of a detecting position, wherein
the arrangement of the raster element is adjusted to a position determined based on a comparison between a minimum value and a maximum value of an intensity of a two-dimensional image obtained by the fluorescent X-rays.
2. An X-ray intensity correction method for correcting an intensity of diffracted X-rays by making a background uniform, the method comprising:
focusing X-rays on a sample for correction placed at a gonio center to produce fluorescent X-rays, entering the fluorescent X-rays excited by the X-rays into a raster element being formed by polycapillaries and having a unique focal point, and detecting the fluorescent X-rays having passed through the raster element; and
adjusting an arrangement of the raster element so that the fluorescent X-rays can uniformly be detected regardless of a detecting position, wherein
the arrangement of the raster element is adjusted until a minimum value become half or more of a maximum value of an intensity of a two-dimensional image obtained by the fluorescent X-rays.
3. The X-ray intensity correction method according to claim 1 , wherein
the arrangement of the raster element is adjusted by moving the raster element in a translation direction and in a tilting direction in accordance with an intensity distribution of the two-dimensional image of the fluorescent X-rays having passed through the raster element.
4. The X-ray intensity correction method according to claim 1 , further comprising:
entering the X-rays diffracted by a sample for measurement into the raster element after the adjustment of arrangement of the raster element and detecting the diffracted X-rays having passed through the raster element while changing the position of the raster element against the diffraction angle of the X-rays.
5. The X-ray intensity correction method according to claim 4 , wherein
the diffracted X-rays having passed through the raster element are detected by moving the raster element in synchronization with TDI scan for detecting the diffracted X-rays.
6. The X-ray intensity correction method according to claim 1 , wherein
a structure for adjusting temperature is provided around the sample and the diffracted X-rays are detected in situ.
7. The X-ray intensity correction method according to claim 1 , wherein
X-rays are entered onto a surface of the sample for measurement at a glazing angle and diffracted X-rays emitted at a glazing angle are detected.
8. An X-ray diffractometer for detecting diffracted X-rays by irradiating a sample with X-rays, the diffractometer comprising:
a raster element formed by polycapillaries and having a unique focal point;
a detector configured to detect X-rays having passed through the raster element; and
an adjusting mechanism configured to enable an adjustment of arrangement of the raster element so that a focal point of the raster element can be set at a gonio center, wherein
the X-rays are detected by oscillating the raster element with the detector,
the raster element is provided to be adjustable independently from the detector with the adjusting mechanism, the adjustment of the arrangement of the raster element is prepared to focus X-rays on a sample for correction placed at a gonio center to produce fluorescent X-rays, entering the fluorescent X-rays excited by the focused X-rays into the raster element, and detecting the fluorescent X-rays having passed through the raster element, and
the arrangement of the raster element is adjusted to a position determined based on a comparison between a minimum value and a maximum value of an intensity of a two-dimensional image obtained by the fluorescent X-rays.
9. The X-ray intensity correction method according to claim 1 , wherein
the arrangement of the raster element is adjusted to a position in case where the minimum value become half or more of the maximum value on the intensity in the two-dimensional image obtained by fluorescent X-rays.
10. The X-ray diffractometer according to claim 8 , wherein
the arrangement of the raster element is adjusted to a position in case where the minimum value become half or more of the maximum value on the intensity in the two-dimensional image obtained by fluorescent X-rays.