IP Library Granted Patent US 9,087,692
Granted Patent B2
US 9,087,692 · App. 13/762,819 · Granted Jul 21, 2015

Method for transferring a graphene layer

Inventors: Corrado Accardi (Ragusa, IT); Stella Loverso (Catania, IT); Sebastiano Ravesi (Catania, IT); Noemi Graziana Sparta (Catania, IT)
Assignee: STMicroelectronics S.r.l.
H01L21/02527B82Y30/00B82Y40/00C01B31/0453C01B31/0484H01L51/00H01L51/003
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Quick Facts
Patent No.
US 9,087,692
App. No.
13/762,819
Granted
Jul 21, 2015
Kind
B2
Abstract

A method transfers a graphene layer from a donor substrate onto a final substrate. The method includes: providing a metal layer on the donor substrate; and growing a graphene layer on the metal layer. The method also includes: laminating a dry film photo-resist on the graphene layer; laminating a tape on the dry film photo-resist; chemically. etching the metal layer, obtaining an initial structure that includes the tape, the dry film photo-resist and the graphene layer; laminating the initial structure on the final substrate; thermally realizing the tape, so as to obtain an intermediate structure that includes the dry film photo-resist, the graphene layer and the final substrate; removing the dry film photo-resist; and obtaining a final structure that includes the final substrate with a transferred graphene layer.

Claims (18)

1. A method, comprising:

providing a metal layer;

growing a graphene layer on said metal layer;

laminating a dry film photo-resist on said graphene layer;

laminating a tape on said dry film photo-resist;

obtaining an initial structure, including said tape, said dry film photo-resist, and said graphene layer, by chemically etching away said metal layer;

laminating said initial structure on a final substrate;

obtaining an intermediate structure, including said dry film photo-resist, said graphene layer, and said final substrate, by thermally releasing said tape from the graphene layer; and

obtaining a final structure, wherein obtaining the final structure includes removing said dry film photo-resist, wherein the dry film photo-resist is a UV-sensitive dry film photo-resist.

2. A method according to claim 1 , wherein removing the dry film photo-resist comprises chemically etching said dry film photo-resist.

3. A method according to claim 1 , wherein obtaining the final structure includes:

patterning said dry film photo-resist by exposing said dry film photo-resist film to ultraviolet light through a mask; and

patterning said graphene layer by chemically etching said graphene layer through the patterned dry film photo-resist.

4. A method according to claim 1 , wherein laminating the dry film photo-resist on said graphene layer comprises laminating a dry film negative photo-resist with a thickness in a range of 10-100μm on said graphene layer.

5. A method according to claim 1 , wherein said metal layer is a nickel layer or a copper layer.

6. A method according to claim 1 , wherein providing said metal layer includes forming the metal layer on a donor substrate that includes at least one of a semiconductor or insulator crystal substrate, a semiconductor device substrate, an epitaxial layer, a flexible substrate, a metal film, and an organic device substrate.

7. A method according to claim 1 , wherein laminating the tape on said dry film photo-resist comprises laminating a thermal releasing tape on said dry film photo-resist.

8. A method according to claim 1 , wherein laminating the tape uses a thermal release tape having a release temperature in the range of 90° C. and 200° C. and a lamination pressure ranging between 2 bar and 5 bar.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 30, 2013
From: ACCARDI, CORRADO; LOVERSO, STELLA; RAVESI, SEBASTIANO; SPARTA, NOEMI GRAZIANA
To: STMICROELECTRONICS S.R.L.
Reel/Frame 030317/0121 →
Priority Claims (1)
IT MI2012A0191 · Feb 10, 2012 · national
Continuity (1)
Related Publication 20130210218A1 · Aug 15, 2013