Hydrolytically-stable hydrophilic coatings for PEMFC bipolar plate
View Patent ↗Bipolar plates useful for fuel cell applications include a plate body having a channel-defining surface that is at least partially coated with a hydrophilic layer. This hydrophilic layer comprises residues of a silane-coupling agent in a sufficient amount such portions of the first hydrophilic layer have a contact angle less than a predetermined value.
1. An electrically conductive bipolar plate for incorporation into a fuel cell, the bipolar plate comprising:
a plate body having a channel-defining surface; and
an activated first layer disposed over at least a portion of the channel-defining surface of the plate body, the activated first layer comprising residues of a silane coupling agent in a sufficient amount such that portions of the channel-defining surface coated with the first activated layer have a contact angle less than a predetermined value, the activated first layer made by a method comprising:
a) contacting the plate body with the silane coupling agent;
b) curing the silane coupling agent to form an unactivated first layer on the plate body; and
c) contacting the unactivated first layer with an acid composition to form the activated first layer
wherein the silane coupling agent has formula I:
Q 2 -Q 1 -Si(R 1 ) 3 I
wherein:
R 1 is an alkoxy or a halogen;
Q 1 is a hydrocarbon-containing moiety providing a spatial separation between Q 1 and the Si(R 1 ) 3 group; and
Q 2 is a moiety having one or more atoms that hydrogen bond or have energetically favorable interactions with water.
2. The bipolar plate of claim 1 wherein the activated first layer is a hydrophilic layer.
3. The bipolar plate of claim 2 wherein the contact angle is less than about 60 degrees.
4. The bipolar plate of claim 2 wherein the contact angle is less than about 30 degrees.
5. The bipolar plate of claim 1 wherein the channel-defining surface defines a set of fluid flow channels configured to distribute flow of a fluid across at least one side of the plate body.
6. The bipolar plate of claim 1 further comprising a second layer disposed over the activated first layer, the second layer being a hydrophilic layer.
7. The bipolar plate of claim 6 wherein the surface coated with the second layer has a contact angle less than about 15 degrees.
8. The bipolar plate of claim 1 wherein the activated first layer includes residues of a colloidal silica.
9. The bipolar plate of claim 1 wherein the silane coupling agent has formula II:
(R 1 ) 3 SiQ 2 Si(R 1 ) 3 II.
10. The bipolar plate of claim 9 wherein the silane coupling agent is bis-1,2-(triethoxysilyl)ethane (“BTSE”).
11. The bipolar plate of claim 1 wherein the silane coupling agent has one or more of the following formulae:
wherein:
X is a halogen; and
m, n, and o are each independently an integer from 0 to 10.
12. The bipolar plate of claim 1 wherein the silane coupling agent has one or more of the following formulae:
13. The bipolar plate of claim 1 wherein the silane coupling agent has the following formula:
wherein:
R 1 is an alkoxy or a halogen; and
n is integer from 0 to 10.
14. The bipolar plate of claim 1 wherein a conductive coating is disposed between the bipolar plate and the activated first layer.
15. A fuel cell comprising the bipolar plate of claim 1 .
16. An electrically conductive bipolar plate for incorporation into a fuel cell, the bipolar plate comprising:
a metal plate body having a channel-defining surface;
a first hydrophilic layer disposed over at least a portion of the channel-defining surface of the plate body, the first hydrophilic layer comprising residues of a silane coupling agent; and
a second hydrophilic layer disposed over the first hydrophilic layer, wherein portions of the plate body covered by the first and second hydrophilic layers have a contact angle less than about 20 degrees
wherein the silane coupling agent has formula I:
Q 2 Q 1 -Si(R 1 ) 3 I
wherein:
R 1 is an alkoxy or a halogen;
Q 1 is a hydrocarbon-containing moiety providing a spatial separation between Q 1 and the Si(R 1 ) 3 group; and
Q 2 is a moiety having one or more atoms that hydrogen bond or have energetically favorable interactions with water.
17. The bipolar plate of claim 16 wherein the second hydrophilic layer includes moieties that hydrogen bond.
18. The bipolar plate of claim 16 wherein the silane coupling agent has formula II:
(R 1 ) 3 SiQ 2 Si(R 1 ) 3 II.
19. The bipolar plate of claim 18 wherein the silane coupling agent is bis-1,2-(triethoxysilyl)ethane (“BTSE”).
20. An electrically conductive bipolar plate for incorporation into a fuel cell, the bipolar plate comprising:
a plate body having a channel-defining surface; and
an activated first layer disposed over at least a portion of the channel-defining surface of the plate body, the activated first layer comprising residues of a silane coupling agent such that portions of the channel-defining surface coated with the activated first layer have a contact angle less than a predetermined value, wherein the silane coupling agent has formulae III, IV, V, VI or VII:
(R 1 ) 3 Si—(CH 2 ) o —Si(R 1 ) 3 III,
X—(CH 2 ) o —Si(OR 1 ) 3 IV,
wherein:
R 1 is an alkoxy or a halogen;
X is a halogen; and
m, n, and o are each independently an integer from 0 to 10.