Gradient thin films

1. A method for making multi-layer gradient composition thin films, the method comprising:

introducing at least one chemical precursor into a plasma wherein the introducing comprises a first chemical precursor and at least one other chemical precursor different from the first chemical precursor;

depositing a thickness of a first film to a surface of a substrate, the first film having a chemical composition derived from the at least one chemical precursor;

modifying at least one plasma-related process parameter related to the deposition of the at least one chemical precursor during the depositing of a thickness of a first film;

varying the chemical composition of at least a portion of the thickness of the first film, independently or in combination, in a vertical direction or in a vertical and horizontal direction relative to the substrate

depositing, within the first film, a thickness of a second film derived at least in part from a second chemical precursor, the second film of a chemical composition different from the first film, at least a portion of the second film being spatially separated from the first film in a horizontal, a vertical, or a horizontal and vertical direction relative to the article surface; and

providing an interface between the first film and the second film, the interface comprising a change in elemental composition of the first film relative to that of the second film, wherein the interface is between a vertical section of the first film and a vertical section the second film, relative to the article surface.

2. The method of claim 1 , wherein the introducing comprises a first chemical precursor and the at least one other chemical precursor different from the first chemical precursor concurrently with the first chemical precursor into the plasma.

3. The method of claim 1 , wherein the introducing comprises a first chemical precursor and the at least one other chemical precursor different from the first chemical precursor subsequently into the plasma.

4. The method of claim 1 , wherein the modifying comprises varying one or more parameters selected from the group consisting of plasma power, carrier gas flow rate, precursor temperature, bubbler flow rate, dilution flow rate, or plasma head vertical position relative to the substrate.

5. The method of claim 1 , wherein the substrate comprises one or more semiconductive materials, metals, or non-metals.

6. The method of claim 1 , wherein the deposition comprises an atmospheric plasma deposition technique.

7. An article comprising

a thickness of a first film comprising silicon-oxy-carbide from a surface of the article; the first film having a gradient chemical composition within at least a portion of the thickness of the first film in a vertical direction, or in a horizontal and vertical direction relative to the surface of the article

a second film different from the first film, the second film present within the first film, the second film of a gradient chemical composition, and at least a portion of the second film being spatially separated from the first film in a horizontal, a vertical, or a horizontal and vertical direction relative to the article surface;

an interface between the first film and the second film, the interface comprising a change in elemental composition of the first film relative to that of the second film; wherein the interface is between a vertical section of the first film and a vertical section the second film, relative to the article surface.

8. The article of claim 7 , wherein the second film is chemically different from the first film in a vertical direction relative to the article surface.

9. The article of claim 7 , wherein the second film is present directly on the first film.

10. The article of claim 7 , wherein the interface between the first film and the second film comprises an elemental composition gradient of one or both of oxygen and carbon.

11. The article of claim 7 , wherein the surface of the article is at least a portion of an aerospace vehicle.

12. An article comprising

a thickness of a first film from a surface of the article; the first film having a gradient chemical composition within at least a portion of the thickness of the first film in a vertical direction, or in a horizontal and vertical direction relative to the surface of the article;

an interface between the first film and a second film, the interface comprising a change in elemental composition of the first film relative to that of the second film, wherein the interface is between a vertical section of the first film and a vertical section the second film, relative to the article surface.

13. The article of claim 12 , wherein the surface of the article is at least a portion of an aerospace vehicle.