Deformable, rigid polystyrene foam board
Provided are methods for producing a high strength, but easily deformed, polystyrene foam board that can endure repeated deformations from its original configuration into more complex curved shapes without damaging the board integrity or substantially reducing its structural strength. Also provided are rigid polystyrene foam boards produced by this method that exhibit improved bending and impact resistance while substantially retaining or improving other properties, for example, the thermal dimensional stability and fire resistance, exhibited by corresponding conventional XPS foam boards. The foamable compositions may incorporate one or more of a variety of polymer processing aids for the purpose of altering the performance of the final foam products, thereby allowing the properties of the final foam product to be customized to some degree.
1. A deformable, non-resilient, closed cell foam board comprising polystyrene and a vinyl resin, wherein the amount of vinyl resin contained in the deformable, non-resilient, closed cell foam board is no greater than 2.5 weight %; and
wherein a transverse sample of the deformable, non-resilient, closed cell foam board having a nominal thickness of 1 inch (about 2.54 cm) exhibits a radius at failure, R f , of from about 1 in (about 2.54 cm) to less than 12 inches (about 30.5 cm).
2. The defonnable, non-resilient, closed cell foam board of claim 1 , wherein the vinyl resin comprises a vinyl polymer having a melt index of 1 to 2 grams/10 minutes at 190° C.
3. The deformable, non-resilient, closed cell foam board of claim 1 , wherein the vinyl resin comprises a vinyl polymer containing 20 to 40 mol % copolymerized vinyl alcohol.
4. The deformable, non-resilient, closed cell foam board of claim 1 , wherein a transverse sample of the deformable, non-resilient, closed cell foam board having a nominal thickness of 1 inch (about 2.54 cm) exhibits a radius at failure, R f , of from about 1 in (about 2.54 cm) to less than 6 inches (about 15.2 cm).
5. The deformable, non-resilient, closed cell foam board of claim 1 , wherein a transverse sample of the deformable, non-resilient, closed cell foam board having a nominal thickness of 1 inch (about 2.54 cm) exhibits a radius at failure, R f , of from about 1 in (about 2.54 cm) to less than 4 inches and a critical radius, R c , of from about 2 in (about 5.08 cm) to less than 6 inches (about 15.2 cm) according to Test Procedure B.
6. The deformable, non-resilient, closed cell foam board of claim 1 , wherein the deformable, non-resilient, closed cell foam board is capable of withstanding repeated deformation.
7. The deformable, non-resilient, closed cell foam board of claim 1 , wherein the vinyl resin is selected from the group consisting of vinyl acetate (EVA), polyvinylalcohol (PVA), vinyl alcohol/ethylene copolymer (EVOH), polyvinylidene chloride (PVDC), polyvinyl chloride (PVC), vinyl chloride/vinylidene chloride copolymer, and vinylidene chloride/methylacrylate copolymer.