IP Library Granted Patent US 9,193,844
Granted Patent B2
US 9,193,844 · App. 14/391,431 · Granted Nov 24, 2015

Mixtures containing trimellitic acid ester and polyether polyol ester as plasticizers, use of the mixtures for producing polymer compounds and PVC materials containing said mixtures

Inventors: Guido D. Frey (Riedstadt, DE); Horst Lange (Bochum, DE); Heinz Strutz (Moers, DE); Jacco de Haas (Krefeld, DE)
Assignee: OXEA GMBH
C08K5/12C08K5/0016C08K5/103C08L71/02
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Quick Facts
Patent No.
US 9,193,844
App. No.
14/391,431
Granted
Nov 24, 2015
Kind
B2
Abstract

A mixture useful as plasticizer comprises trimellitic esters and polyether polyol esters, characterized in that the mixture comprises from 1 to 99% by weight of trimellitic esters and 99 to 1% by weight of polyether polyol esters, wherein the polyether polyol esters can be derived from linear or branched, aliphatic monocarboxylic acids having 3 to 20 carbon atoms in the molecule.

Claims (11)

1. Mixture comprising trimellitic esters and polyether polyol ester, characterized in that the mixture comprises from 51-84.5% by weight of trimellitic esters and 49-15.5% by weight of a polyether polyol ester, wherein the polyether polyol ester is triethylene glycol di-2-ethylhexanoate and further characterized in that trimellitic esters are selected from tri(2-ethylhexyl) trimellitate, tri(n-octyl, n-decyl) trimellitate, tri(heptyl, nonyl) trimellitate, tri(n-octyl) trimellitate, tri(isononyl) trimellitate, tri(isodecyl) trimellitate or mixtures thereof.

2. Mixture according to claim 1 , characterized in that the mixture consists of tri(2-ethylhexyl) trimellitate and triethylene glycol di-2-ethylhexanoate.

3. Mixture according to claim 1 , characterized in that the mixture has a viscosity of <300 mm 2 /s at 20° C. and <80 mm 2 /s at 40° C.

4. PVC materials comprising the mixture according to Claim 1 , characterized in that the PVC materials have a glass transition temperature of <20° C.

5. PVC materials comprising the mixture according to claim 1 , characterized in that the PVC materials have a fogging number of at least 60.

6. A method using the mixture according to claim 1 comprising incorporating the mixture into polymer compounds having a Shore A hardness of <90.

7. A method using the mixture according to claim 1 comprising incorporating the mixture into a product selected from the group consisting of: polymer compounds; masterbatches; semifinished products and finished products.

8. The method according to claim 7 , wherein the product comprises PVC.

9. The method according to claim 8 , wherein the mixture consists of tri(2-ethylhexyl) trimellitate and triethylene glycol di-2-ethylhexanoate.

10. A product comprising PVC and provided with a mixture comprising from 51-84.5% by weight of trimellitic esters and 49-15.5% by weight of a polyether polyol ester, wherein the polyether polyol ester is triethylene glycol di-2-ethylhexanoate, wherein further the trimellitic esters are selected from tri(2-ethylhexyl) trimellitate, tri(n-octyl, n-decyl) trimellitate, tri(heptyl, nonyl) trimellitate, tri(n-octyl) trimellitate, tri(isononyl) trimellitate, tri(isodecyl) trimellitate or mixtures thereof.

11. The product according to claim 10 , characterized in that the mixture consists of tri(2-ethylhexyl) trimellitate and triethylene glycol di-2-ethylhexanoate.

Assignments (2)
CHANGE OF NAME Recorded Aug 25, 2021
From: OXEA GMBH
To: OQ CHEMICALS GMBH
Reel/Frame 057312/0979 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 9, 2014
From: FREY, GUIDO D.; LANGE, HORST; STRUTZ, HEINZ; DE HAAS, JACCO
To: OXEA GMBH
Reel/Frame 033981/0552 →
Priority Claims (1)
DE 10 2012 012 942 · Jun 29, 2012 · national
Continuity (1)
Related Publication 20150105507A1 · Apr 16, 2015