IP Library Granted Patent US 9,205,375
Granted Patent B2
US 9,205,375 · App. 12/235,482 · Granted Dec 8, 2015

Removing carbon dioxide from waste streams through co-generation of carbonate and/or bicarbonate minerals

Inventors: Joe David Jones (Austin, TX); David St. Angelo (Austin, TX)
Assignee: SKYONIC CORPORATION
B01D53/62B01D53/73B01D53/75B01D53/965C01B7/01C01B7/03C01B7/035C01B7/04C01B9/02C01B11/062C01F11/24B01D2251/304B01D2251/502B01D2251/604B01D2257/302B01D2257/404B01D2257/504B01D2257/602Y02C10/04Y02C10/06Y02W10/37
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Quick Facts
Patent No.
US 9,205,375
App. No.
12/235,482
Granted
Dec 8, 2015
Kind
B2
Abstract

Apparatuses and methods for removing carbon dioxide and other pollutants including heavy metals from a gas stream are provided. The methods include obtaining a water-condensate from the flue-gas stream; obtaining a chloride salt; admixing the salt with water, steam, or both to produce a solution; electrolyzing the solution to produce a hydroxide and chlorine gas; admixing a portion of the hydroxide with the flue-gas stream to produce carbonate products, bicarbonate products, or a mixture of carbonate and bicarbonate products in an admixture; separating said carbonate and/or bicarbonate products from the admixture, thereby removing carbon dioxide from the flue-gas stream; adding a portion of the hydroxide to the water-condensate to change the pH of the water-condensate from acidic to basic, resulting in precipitation of the heavy metals; and passing the water-condensate through a filtering medium.

Claims (17)

1. A method of separating heavy metals and carbon dioxide from an incoming flue-gas stream, comprising:

obtaining a water-condensate containing heavy metals from the incoming flue-gas stream, thereby producing a dry flue-gas stream;

obtaining a chloride salt;

admixing the salt with water, steam, or both to produce a solution;

electrolyzing the solution to produce a hydroxide and chlorine gas;

admixing a portion of the hydroxide with the dry flue-gas stream to produce carbonate products, bicarbonate products, or a mixture of carbonate and bicarbonate products in an admixture;

separating said carbonate and/or bicarbonate products from the admixture, thereby removing carbon dioxide from the incoming flue-gas stream;

adding to the water-condensate a precipitation agent comprising a portion of the hydroxide to change the pH of the water-condensate from acidic to basic,

resulting in precipitation of the heavy metals; and

passing the water-condensate through a filtering medium.

2. The method of claim 1 , wherein the filtering medium comprises activated charcoal.

3. The method of claim 1 , wherein the condensate is gravity-fed through the filtering medium.

4. The method of claim 1 , wherein the condensate is actively pumped through the filtering medium.

5. The method of claim 1 , wherein the precipitation agent consists of the portion of the hydroxide.

6. The method of claim 1 , wherein the heavy metals comprise mercury and one or more heavy metals selected from a group consisting of selenium, chromium, arsenic, lead, germanium, and vanadium.

7. The method of claim 1 , wherein obtaining a water-condensate from the incoming flue-gas stream comprises separating the water condensate from the incoming flue-gas stream.

8. The method of claim 1 , wherein the hydroxide used as the precipitation agent is formed solely from the electrolyzing step.

Assignments (4)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 25, 2019
From: SKYONIC CORPORATION
To: SKYONIC (ASSIGNMENT FOR THE BENEFIT OF CREDITORS), LLC
Reel/Frame 050483/0581 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Dec 23, 2016
From: SKYONIC (ASSIGNMENT FOR THE BENEFIT OF CREDITORS), LLC
To: CARBONFREE CHEMICALS HOLDINGS, LLC
Reel/Frame 041187/0407 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 29, 2010
From: ST. ANGELO, DAVID
To: SKYONIC CORPORATION
Reel/Frame 024759/0249 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 6, 2009
From: JONES, JOE DAVID
To: SKYONIC CORPORATION
Reel/Frame 022063/0771 →
Continuity (4)
Provisional Application 60973948 · Sep 20, 2007
Provisional Application 61032802 · Feb 29, 2008
Provisional Application 61033298 · Mar 3, 2008
Related Publication 20090127127A1 · May 21, 2009