Low resistivity ohmic contact
Embodiments of a low resistivity ohmic contact are disclosed. In some embodiments, a method of fabricating a low resistivity ohmic contact includes providing a semiconductor material layer and intentionally roughening the semiconductor material layer to create a characteristic surface roughness. The method also includes providing an ohmic contact metal layer on a surface of the semiconductor material layer and providing a diffusion barrier metal layer on a surface of the ohmic contact metal layer opposite the semiconductor material layer. In this way, the adhesive force between the semiconductor material layer and the ohmic contact metal layer may be increased.
1. A method of fabricating a low resistivity ohmic contact comprising:
providing a semiconductor material layer that is an alloy of Bismuth Telluride;
intentionally roughening the semiconductor material layer to create a characteristic surface roughness that has an R a =0.1 μm to 2 μm, where R a is the arithmetic average of a roughness profile of the semiconductor material layer;
providing an adhesion metal layer on the surface of the semiconductor material layer;
providing an ohmic contact metal layer on a surface of the adhesion metal layer; and
providing a diffusion barrier metal layer on a surface of the ohmic contact metal layer opposite the semiconductor material layer.
2. The method of claim 1 wherein the characteristic surface roughness has an R a =0.75 μm to 1.25 μm.
3. The method of claim 1 wherein the semiconductor material layer is chosen from the group consisting of Bi 2 (Te x Se 1-x ) 3 and (Sb y Bi 1-y ) 2 {Te x Se 1-x ) 3 where 0<x<1 and 0<y<1.
4. The method of claim 1 wherein the semiconductor material layer has a carrier concentration between 1*10 19 carriers/cm 3 to 3*10 21 carriers/cm 3 .
5. The method of claim 4 wherein the semiconductor material layer has a carrier concentration between 1*10 20 carriers/cm 3 to 1*10 21 carriers/cm 3 .
6. The method of claim 1 wherein the ohmic contact metal layer is chosen from the group consisting of Nickel, Cobalt, an alloy of Nickel, and an alloy of Cobalt.
7. The method of claim 6 wherein the ohmic contact metal layer is Cobalt.
8. The method of claim 1 wherein the adhesion metal layer is chosen from the group consisting of the transition metals.
9. The method of claim 1 wherein the adhesion metal layer is between 1 and 20 nm thick.
10. The method of claim 9 wherein the adhesion metal layer is between 5 and 10 nm thick.
11. The method of claim 1 wherein the diffusion barrier metal layer is Nickel.
12. The method of claim 1 further comprising cleaning the surface of the semiconductor material layer.
13. A low resistivity ohmic contact comprising:
a semiconductor material layer that is an alloy of Bismuth Telluride with a surface roughness R a =0.1 μm to 2 μm, where R a is the arithmetic average of a roughness profile of the semiconductor material layer;
an adhesion metal layer on the surface of the semiconductor material layer;
an ohmic contact metal layer on a surface of the adhesion metal layer; and
a diffusion barrier metal layer on a surface of the ohmic contact metal layer opposite the semiconductor material layer.
14. The low resistivity ohmic contact of claim 13 wherein:
the semiconductor material layer has a carrier concentration between 1*10 19 carriers/cm 3 to 3*10 21 carriers/cm 3 ;
the adhesion metal layer is chosen from the group consisting of the transition metals and is between 1 and 20 nm thick;
the ohmic contact metal layer is Cobalt; and
the diffusion barrier metal layer is Nickel.