Surface treatment to passivate sublimation surfaces to hydrophobic contaminants
The sublimation capability of a porous metal plate used in a sublimator is maintained by heating the porous metal plate at an elevated temperature in a flowing stream of oxygen for an extended period of time to form an oxidized surface. A short chain molecule, such as citric acid, is attached to the oxidized surface having multiple functional carboxylate groups and no hydrophobic tail.
1. A sublimator porous plate comprising:
a porous metal plate having a porous passivated surface consisting essentially of:
a first passivated portion including an uncharged oxide; and
a second passivated portion including a plurality of short chain molecules attached to metal cations, each short chain molecule having multiple functional carboxylate groups and no hydrophobic tail.
2. The sublimator porous plate of claim 1 , wherein the uncharged oxide is formed at an elevated temperature, and the elevated temperature ranges from about 900° F. (482° C.) to about 1200° F. (649° C.), wherein the plurality of short chain molecules include a four carbon or less organic acid having at least one carboxylate group.
3. The sublimator porous plate of claim 1 , wherein the porous plate is made from a metal selected from the group consisting of stainless steel and nickel based alloys.
4. The sublimator porous plate of claim 3 , wherein the porous plate is made from stainless steel.
5. The sublimator porous plate of claim 2 , wherein the porous plate is heated to maintain the elevated temperature for at least four hours.
6. The sublimator porous plate of claim 1 , wherein the plurality of short chain molecules include citric acid.
7. The sublimator porous plate of claim 1 , wherein the porous plate is submerged in a dilute solution of citric acid for at least two hours.
8. The sublimator porous plate of claim 7 , wherein the dilute solution is less than 0.1 molar citric acid in water.