IP Library Granted Patent US 9,233,875
Granted Patent B2
US 9,233,875 · App. 13/431,018 · Granted Jan 12, 2016

Polyelectrolytic flow agent

Inventors: Frank Dierschke (Oppenheim, DE); Michael Schinabeck (Altenmarkt, DE)
Assignee: BASF Construction Solutions GmbH
C04B24/246C04B24/2652C04B28/14C04B2103/30
View Patent ↗
Loading inventors, assignments & file history…
Monitor This Case
Get email alerts when status or documents change.
Order Certified Copies
Most orders are placed with the USPTO same day — all within 24 business hours.
Order via The Patent Place →
Pre-filled with this patent's details
Quick Facts
Patent No.
US 9,233,875
App. No.
13/431,018
Granted
Jan 12, 2016
Kind
B2
Abstract

The invention provides compositions containing a salt formed from an acid and from a base, wherein the acid is defined as a polycondensation product containing (I) at least one structural unit including an aromatic or heteroaromatic and a polyether side chain, and (II) at least one phosphated structural unit including an aromatic or heteroaromatic, and polyethyleneimine as base, wherein the molar mass of the polyethyleneimine is greater than 500 daltons. Likewise provided is a process for producing these compositions and building product mixtures comprising the invention compositions. The invention also provides for the use of the compositions as admixture agents, preferably as flow agents, for aqueous suspensions of binders based on calcium sulphate or for aqueous suspensions of (latently) hydraulic binders.

Claims (46)

1. A composition comprising a salt formed from an acid and from a base,

wherein the acid is defined as a polycondensation product containing

(I) at least one structural unit including an aromatic or heteroaromatic and a polyether side chain, and

(II) at least one phosphated structural unit including an aromatic or heteroaromatic, and

polyethyleneimine as base,

wherein the molar mass of the polyethyleneimine is greater than 500 daltons,

wherein the mass ratio of the acidic polycondensation product to the base polyethyleneimine is in the range from 4:1 to 100:1.

2. The composition according to claim 1 , wherein the structural units (I) and (II) are represented by the following formulae:

wherein

A is identical or different and is also represented by a substituted or unsubstituted aromatic or heteroaromatic compound with 5 to 10 carbon atoms, wherein the 5 to 10 carbon atoms are preferably in the aromatic ring system,

with

B is identical or different and also represented by N, NH or O

wherein

n is 2 when B is N and wherein n is 1 when B is NH or O; wherein

R 1 and R 2 each independently identical or different and also represented by a branched or unbranched C 1 - to C 10 -alkyl radical, C 5 - to C 8 -cycloalkyl radical, aryl radical, heteroaryl radical or H

wherein a is identical or different and also represented by an integer from 1 to 300,

wherein X is identical or different and also represented by a branched or unbranched C 1 - to C 10 -alkyl radical, C 5 - to C 8 -cycloalkyl radical, aryl radical, heteroaryl radical or H; and

wherein D identical or different and also represented by a substituted or unsubstituted aromatic or heteroaromatic compound with 5 to 10 carbon atoms, wherein the 5 to 10 carbon atoms are preferably in the aromatic ring system,

wherein E is identical or different and also represented by N, NH or O;

wherein m is 2 when E is N and wherein m is 1 when E is NH or 0;

wherein R 3 and R 4 each independently identical or different and also represented by a branched or unbranched C 1 - to C 10 -alkyl radical, C 5 - to C 8 -cycloalkyl radical, aryl radical, heteroaryl radical or H

wherein b is identical or different and also represented by an integer from 0 to 300.

3. A composition according to claim 1 , wherein the acid contains a further structural unit (III) which is represented by the following formula:

wherein Y are each independently identical or different and represented by (I), (II), or further constituents of the polycondensation product

wherein R 5 identical or different and represented by H, CH 3 , COOH or a substituted or unsubstituted aromatic or heteroaromatic compound with 5 to 10 carbon atoms wherein the 5 to 10 carbon atoms are preferably in the aromatic ring system,

and wherein R 6 identical or different and represented by H, CH 3 , COOH or a substituted or unsubstituted aromatic or heteroaromatic compound with 5 to 10 carbon atoms wherein the 5 to 10 carbon atoms are preferably in the aromatic ring system.

4. A composition according to claim 3 , wherein R 5 and R 6 in structural unit (III) are each independently represented, identically or differently, by a member selected from the group consisting of H, COOH and methyl.

5. A composition according to claim 1 , wherein the molar ratio of structural units [(I)+(II)]:(III) is 1:0.8 to 3.

6. A composition according to claim 1 , wherein the molar ratio of structural units (I):(II) is in the range from 1:10 to 10:1.

7. A composition according to claim 1 , wherein the composition contains 2% to 90% by weight of water and 98% to 10% by weight of dissolved dry matter.

8. A composition according to claim 1 , wherein the molar mass of the base polyethyleneimine is in the range of from 800 to 30,000 g/mol.

9. A composition according to claim 1 , wherein the mass ratio of the acid polycondensation product to the base polyethyleneimine is in the range from 7:1 to 20:1.

10. A composition according to claim 1 , further comprising further bases.

11. A composition according of claim 10 , wherein the composition comprises greater than 25% by weight polyethyleneimine.

12. A process for producing a composition according to claim 1 , which process comprises the steps of:

a) reacting under acidic pH a reaction mixture comprising

(Ia) a monomer including a polyether side chain and an aromatic or heteroaromatic,

(IIa) at least one phosphated monomer including an aromatic or heteroaromatic, and

(IIIa) at least one keto compound as monomer of the formula

wherein R 7 is identical or different and represented by H, CH 3 , COOH or a substituted or unsubstituted aromatic or heteroaromatic compound with 5 to 10 carbon atoms wherein the 5 to 10 carbon atoms are preferably in the aromatic ring system, with R 8 is identical or different and represented by H, CH 3 , COOH or a substituted or unsubstituted aromatic or heteroaromatic compound with 5 to 10 carbon atoms wherein the 5 to 10 carbon atoms are preferably in the aromatic ring system, to form the acidic polycondensation product, and

b) mixing the acidic polycondensation product with the base polyethyleneimine.

13. A building product mixture containing compositions according to claim 1 and a binder based on calcium sulphate or a hydraulic binder.

14. A method of regulating the flow of an aqueous suspension of a binder based on calcium sulphate comprising adding to the aqueous suspension of sufficient amount of the composition of claim 1 to control the flow of said aqueous suspension.

15. A composition comprising a hydraulic binder and the composition of claim 1 .

16. A composition according to claim 1 , wherein the molar mass of the base polyethyleneimine is in the range of from 1,200 to 26,000 g/mol.

17. A composition according to claim 9 , wherein the mass ratio of the acidic polycondensation product to the base polyethyleneimine is in the range from 4:1 to 20:1.

Assignments (4)
CORRECTIVE ASSIGNMENT TO CORRECT THE ASSIGNEE NAME PREVIOUSLY RECORDED AT REEL: 038385 FRAME: 0369. ASSIGNOR(S) HEREBY CONFIRMS THE CHANGE OF NAME. Recorded May 9, 2016
From: BASF CONSTRUCTION CHEMICALS GMBH
To: BASF CONSTRUCTION SOLUTIONS GMBH
Reel/Frame 038746/0890 →
CHANGE OF NAME Recorded Apr 26, 2016
From: BASF CONSTRUCTION CHEMICALS GMBH
To: BASF CONSTRUCTION SOLUTIONS
Reel/Frame 038385/0369 →
MERGER Recorded Apr 21, 2016
From: BASF CONSTRUCTION POLYMERS GMBH
To: BASF CONSTRUCTION CHEMICALS GMBH
Reel/Frame 038338/0529 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 28, 2012
From: DIERSCHKE, FRANK; SCHINABECK, MICHAEL
To: BASF CONSTRUCTION POLYMERS GMBH
Reel/Frame 027964/0591 →
Continuity (2)
Provisional Application 61473180 · Apr 8, 2011
Related Publication 20120255464A1 · Oct 11, 2012