Porous carbon interlayer for lithium-sulfur battery
The present disclosure relates to an electrochemical cell including an anode, a sulfur-containing cathode, a lithium-ion-containing electrolyte, and a porous carbon interlayer disposed between the anode and the cathode. The interlayer may be permeable to the electrolyte. The interlayer may be formed from a multiwall carbon nanotube (MWCNT) or a microporous carbon paper (MCP).
1. An electrochemical cell comprising:
an anode,
a sulfur-containing cathode,
a lithium-ion-containing electrolyte, and
a free-standing porous multiwall carbon nanotube (MWCNT) carbon interlayer disposed between the anode and the cathode, wherein the interlayer is permeable to the electrolyte and which comprises non-uniform pores of an average size between 50 nm and 100 nm.
2. An electrochemical cell comprising:
an anode,
a sulfur-containing cathode,
a lithium-ion-containing electrolyte, and
a free-standing microporous carbon paper (MCP) carbon interlayer disposed between the anode and the cathode, wherein the interlayer is permeable to the electrolyte and comprises uniform pores of an average size of less than 50 nm.
3. The cell of claim 2 , wherein the MCP interlayer comprises uniform pores of an average size of less than 10 nm.
4. The cell of claim 2 , wherein the MCP interlayer comprises uniform pores of an average size of less than 5 nm.
5. The cell of claim 1 , wherein the carbon interlayer is not permeable to electrolyte-soluble polysulfides formed at the sulfur-containing cathode.
6. The cell of claim 2 , wherein the carbon interlayer is not permeable to electrolyte-soluble polysulfides formed at the sulfur-containing cathode.
7. The cell of claim 1 , wherein the anode is a lithium metal anode.
8. The cell of claim 1 , wherein the anode is a carbon anode.
9. The cell of claim 2 , wherein the anode is a lithium metal anode.
10. The cell of claim 2 , wherein the anode is a carbon anode.
11. The cell of claim 1 , further comprising a separator disposed between the carbon interlayer and the anode.
12. The cell of claim 2 , further comprising a separator disposed between the carbon interlayer and the anode.
13. The cell of claim 1 , wherein the cathode has less resistance to charge transfer than a cathode in an otherwise identical cell lacking the carbon interlayer.
14. The cell of claim 2 , wherein the cathode has less resistance to charge transfer than a cathode in an otherwise identical cell lacking the carbon interlayer.
15. The cell of claim 1 , wherein the carbon interlayer comprises absorbed sulfur.
16. The cell of claim 1 , wherein the carbon interlayer comprises absorbed sulfur.
17. The cell of claim 2 , wherein the MCP carbon interlayer comprises carbon nanoparticles between 20 nm and 40 nm in size.