Cathode active material, and cathode and lithium battery including the material
A cathode active material including a lithium metal oxide represented by Formula 1: Li[Li x Me y M′ z ]O (2+d) Formula 1 wherein x+y+z=1, 0<x<0.33, 0<z≦0.1, and 0≦d≦0.1, Me is at least one metal selected from Mn, V, Cr, Fe, Co, Ni, Al, and B, and M′ is at least one metal selected from Sc, Y, and La.
1. A cathode active material comprising a lithium metal oxide represented by Formula 1:
Li[Li x Me y M′ z ]O (2+d) Formula 1
wherein
x+y+z=1, 0<x<0.33, 0<z≦0.1, and 0≦d≦0.1,
Me is at least one metal selected from Mn, V, Cr, Fe, Co, Ni, Al and B, and
M′ is [at least one metal selected from] Sc[, and Y].
2. The cathode active material of claim 1 , wherein z satisfies the inequality 0.005≦z≦0.05.
3. The cathode active material of claim 1 , wherein Me comprises:
at least one metal selected from V, Cr, Fe, Co, Ni, Al, and B; and
Mn.
4. The cathode active material of claim 1 , wherein an amount of Mn is in a range of about 20 to about 80 mole percent, based on a total number of moles of [Li x Me y M′ z ] in the lithium metal oxide of Formula 1.
5. The cathode active material of claim 1 , wherein the lithium metal oxide is represented by Formula 3:
Li[Li x Ni a Co b Mn c M′ z ]O (2+d) Formula 3
wherein x+a+b+c+z=1, 0<x<0.33, 0<z≦0.1,0<a≦0.5, 0<b≦0.5, 0.2≦c≦0.8, and 0≦d≦0.1, and
M′ is Sc [or Y].
6. The cathode active material of claim 5 , wherein z satisfies the inequality 0.005≦z≦0.05.
7. The cathode active material of claim 1 , wherein the lithium metal oxide is represented by Formula 4:
Li[Li x Ni a Co b Mn c M′ z ]O (2+d) Formula 4
wherein x+a+b+c+z=1, 0.1<x<0.2, 0<z≦0.1,0<a≦0.3, 0<b≦0.3, 0.4≦c≦0.6, and 0≦d≦0.1, and
M′ is Sc [or Y].
8. The cathode active material of claim 7 , wherein z satisfies the condition of 0.005≦z≦0.05.
9. The cathode active material of claim 1 , wherein the lithium metal oxide is represented by Formula 5:
Li[Li x Ni a Co b Mn c Sc z ]O (2+d) Formula 5
wherein x+a+b+c+z=1, 0.1<x<0.2, 0.005≦z≦0.1, 0<a≦0.3, 0<b≦0.3, 0.4≦c≦0.6, and 0≦d≦0.1.
10. A cathode comprising the cathode active material of claim 1 .
11. A lithium battery comprising the cathode of claim 10 .