High T
A thermoset resin, including the reaction product of: an epoxy resin mixture including at least one cycloaliphatic epoxy resins; a cycloaliphatic anhydride hardener; and a catalyst; wherein the reaction product has a glass transition temperature greater than or equal to 210° C. Also disclosed is a process for forming a thermoset resin, including: admixing two or more epoxy resins and a cycloaliphatic anhydride hardener to form a curable composition, wherein the epoxy resins include at least one cycloaliphatic epoxy resin; thermally curing the curable composition at a temperature of at least 150° C. to result in a thermoset resin having a glass transition temperature of at least 210° C. Such curable compositions may include: 35 to 65 weight percent of an epoxy resin mixture having at least one cycloaliphatic epoxy resins; 35 to 65 weight percent of a cycloaliphatic anhydride hardener; and from greater than 0 to 10 weight percent of a catalyst.
1. A curable composition comprising an epoxy resin mixture, wherein the epoxy resin mixture comprises 70 weight percent to 100 weight percent of cycloaliphatic epoxy resins based on a total weight of the epoxy resin mixture; a cycloaliphatic anhydride hardener; greater than 10 to 30 weight percent of a toughening agent based on the total weight of the curable composition; and a catalyst that includes a metal carboxylate salt.
2. The curable composition of claim 1 , wherein the curable composition includes from about 35 to about 65 weight percent of the cycloaliphatic anhydride hardener; and from 0.01 to about 10 weight percent of the catalyst; and wherein the weight percentages given are based on the combined weight of the epoxy resin mixture, hardener, toughening agent, and catalyst.
3. The curable composition of claim 1 , wherein the cycloaliphatic anhydride hardener is nadic methyl anhydride.
4. The curable composition of claim 1 , further including at least one of an epoxy phenolic novolac resin, an epoxy bisphenol-A novolac resin, a multifunctional epoxy resin, a bisphenol-A based epoxy resin, a bisphenol-F based epoxy resin, a polyether polyol or a combination thereof.
5. The curable composition of claim 1 , where the toughening agent includes a rubber compound.
6. The curable composition of claim 1 , wherein the catalyst further includes at least one tertiary amine, phosphonium salt, ammonium salt, imidazole, metal oxide or a combination thereof.
7. A toughened thermoset resin, comprising the reaction product of the curable composition of claim 1 .
8. The curable composition of claim 1 , wherein the curable composition when cured forms a reaction product, the resulting reaction product having (i) a glass transition temperature greater than or equal to about 210° C. as measured by differential scanning calorimetry or dynamic mechanical thermal analysis; (ii) a tensile modulus of at least about 260000 psi; (iii) an elongation at break of at least about 5 percent; and (iv) a peak stress of at least about 7000 psi.