Thermally conductive silicone grease composition
The present invention provides a thermally conductive grease composition which scarcely increases in hardness during high-temperature heating and has a minimized reduction in growth, containing: (A) an organopolysiloxane including at least two alkenyl groups per molecule, the 25° C. kinetic viscosity being 5,000 to 100,000 mm 2 /s; (B) a hydrolysable methyl polysiloxane, trifunctional at one terminus, represented by general formula (1) (R 1 is a C 1-6 alkyl group, and a is an integer 5 to 100); (C) a thermally conductive filler having a thermal conductivity of 10 W/m·° C. or greater; (D) an organohydrogenpolysiloxane containing two to five hydrogen atoms directly bonded to a silicon atom (Si—H group) per molecule; (E) an adhesion promoter having a triazine ring and at least one alkenyl group per molecule; and (F) a catalyst selected from the group consisting of platinum and platinum compounds.
1. A thermally conductive silicone grease composition comprising:
(A) 100 parts by weight of an organopolysiloxane having at least two alkenyl groups in one molecule and having a kinetic viscosity of 5,000 to 100,000 mm 2 /s at 25° C.;
(B) more than 50 parts to 90 parts by weight of a hydrolyzable methylpolysiloxane having a trifunctional termination at one end and represented by formula (2):
wherein R 2 represents an alkyl group having 1 to 6 carbon atoms and b is an integer of 5 to 100;
(C) 500 to 1,500 parts by weight of a thermally conductive filler having a thermal conductivity of at least 10 W/m·° C.;
(D) an organohydrogenpolysiloxane having from 2 to 5 hydrogen atoms directly bound to silicon atoms (Si—H groups) in such an amount that the number of Si—H groups/the number of the alkenyl groups of said component (A)=1.7 to 2.8;
(E) 0.05 to 0.5 parts by weight of a bonding aid having a triazine ring and at least one alkenyl group in one molecule; and
(F) a catalyst selected from the group consisting of platinum and a platinum compound in an amount of 0.1 to 500 ppm of a platinum atom relative to said component (A).
2. The thermally conductive silicone grease composition according to claim 1 , further comprising 0.05 to 0.5 parts by weight, per 100 parts by weight of said component (A), of (G) an inhibiting agent selected from the group consisting of an acetylene compound, a nitrogen compound, an organophosphorus compound, an oxime compound, and an organochloro compound.
3. The thermally conductive silicone grease composition of claim 1 , wherein when a sheet obtained by curing the thermally conductive silicone grease composition at 150° C. for 90 minutes is measured according to a method described in JIS K6251, an elongation at breakage is at least 100% and when said composition is shaped into a 2 mm thick sheet and aged at 150° C. for 1,000 hours, an elongation at breakage is at least 80%.
4. The thermally conductive silicone grease composition according to claim 2 , comprising said acetylene compound.
5. The thermally conductive silicone grease composition according to claim 2 , comprising said nitrogen compound.
6. The thermally conductive silicone grease composition according to claim 2 , comprising said organophosphorus compound.
7. The thermally conductive silicone grease composition according to claim 2 , comprising said oxime compound.
8. The thermally conductive silicone grease composition according to claim 2 , comprising said organochloro compound.
9. The thermally conductive silicone grease composition according to claim 1 , wherein said component (A) is a dimethylpolysiloxane blocked with a dimethylvinylsilyl group at both ends.
10. The thermally conductive silicone grease composition according to claim 1 , wherein said component (D) is present in such an amount that the number of Si—H groups/the number of the alkenyl groups of said component (A)=2.0 to 2.5.