Filled porous membrane
A porous membrane may have a high concentration of spherical fillers with a polymer binder. The polymer binder may have an affinity for the filler materials and may hold the filler materials together in a porous structure with high tortuosity and consistent pore size. The membrane may be manufactured with a reinforcing web, such as non-woven web. The membrane may be greater than 50% porous with a less than 1 micron pore size. Within the pore walls that may be less than 0.02 microns in width, a densely packed filler material may have an average diameter of less than 0.005 microns.
1. A filled porous non-adsorption membrane comprising:
a polymer binder;
one or more filler material(s) comprising at least one spherical filler material;
said membrane having:
at least 10% by volume of said at least one spherical filler material by total volume of the porous membrane;
a greater than 2:1 pore diameter to particle diameter dimensional ratio; and
pore wall thickness greater than the maximum particle dimension of any of the one or more filler material(s).
2. The membrane of claim 1 further comprising a non-woven web.
3. The membrane of claim 1 , said at least one spherical filler material being non-adsorbent.
4. The membrane of claim 3 , said at least one spherical filler material being a non-organic filler material.
5. The membrane of claim 1 wherein said one or more filler material(s) further comprise at least one non-spherical filler material.
6. The membrane of claim 5 , said at least one non-spherical filler material being non-adsorbent.
7. The membrane of claim 6 , said at least one non-spherical filler material having a maximum dimension greater than an average pore diameter for said membrane.
8. The membrane of claim 7 , said at least one non-spherical filler material having an average maximum dimension at least 5 times said average pore diameter.
9. The membrane of claim 1 , said polymer being one of a group composed of polyethylene, polypropylene, PET, PVDF, acrylic, PVC, and amide.
10. The membrane of claim 1 further having a greater than 0.001 micron filler material particle size.
11. The membrane of claim 10 further having a greater than 2:1 pore diameter to filler material particle diameter dimensional ratio.
12. The membrane of claim 11 further having a greater than 5:1 pore diameter to pore wall thickness dimensional ratio.
13. A filled microporous non-adsorption membrane comprising:
a polymer binder comprising PVDF;
one or more filler material(s) comprising at least one spherical filler material, said first at least one spherical filler material being non-organic;
a reinforcement being a non-woven web;
said membrane having:
at least 50% of said at least one spherical filler material by weight; and
a cell wall thickness greater than the maximum particle dimension of any of the one or more filler material(s).
14. The membrane of claim 13 wherein said at least one spherical filler material is TiO2.
15. The membrane of claim 14 wherein said one or more filler material(s) further comprise at least one fibrous filler material, said at least one fibrous filler material being Wollastonite.
16. A filled porous non-adsorption membrane comprising:
a polymer binder;
one or more filler material(s) comprising at least one spherical filler material;
said membrane having:
at least 10% by volume of said at least one spherical filler material by total volume of the porous membrane;
a less than 5 mm average pore size;
a greater than 0.02 micron average pore wall thickness; and
pore wall thickness greater than the maximum particle dimension of any of the one or more filler material(s).
17. The membrane of claim 16 further comprising a non-woven web.
18. The membrane of claim 17 , said at least one spherical filler material being non-adsorbent.
19. The membrane of claim 16 , said at least one spherical filler material being a non-organic filler material.
20. The membrane of claim 19 , said non-organic filler material being non-adsorbent.