IP Library Granted Patent US 9,359,321
Granted Patent B2
US 9,359,321 · App. 14/366,276 · Granted Jun 7, 2016

Hydroxymethylfurfural derivative

Inventors: Hiroshi Nishioka (Hokkaido, JP); Tomohiro Ito (Hokkaido, JP); Takahiro Maeda (Hokkaido, JP)
Assignee: AMINO UP CHEMICAL CO., LTD
C07D307/48A23L1/2128A23L1/3002A61K36/8965C07D307/50C07D405/12
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Quick Facts
Patent No.
US 9,359,321
App. No.
14/366,276
Granted
Jun 7, 2016
Kind
B2
Abstract

The hydroxymethylfurfural derivative is represented by the general formula (A) (wherein, R is selected from the group consisting of the following formula (I), (II) HOOCCH 2 COCO—, (III) HOOCCH 2 CH 2 COCO—, and (IV) a hydrogen atom).

Claims (12)

1. A purified hydroxymethylfurfural derivative represented by the following general formula:

wherein R is selected from the group consisting of formula (I):

(II): HOOCCH 2 COCO—, and (III): HOOCCH 2 CH 2 COCO—.

2. The purified hydroxymethylfurfural derivative according to claim 1 , wherein the hydroxymethylfurfural derivative is obtained by heat-treating an asparagus stem with hot water and an enzyme treatment,

wherein the enzyme treatment is carried out by adding at least one enzyme selected from among a group consisting of cellulase, hemicellulase, pectinase, amylase and pullulanase; and treating at a temperature of 30 to 60° C. for 1 to 72 hours.

3. A method of producing a hydroxymethylfurfural derivative of the following formula:

wherein R is selected from the group consisting of formula (I):

(II): HOOCCH 2 COCO—, (III): HOOCCH 2 CH 2 COCO—, and (IV): a hydrogen atom, comprising a step of heat-treating an asparagus stem with hot water and a step of an enzyme treatment,

wherein the enzyme treatment is carried out by adding at least one enzyme selected from among a group consisting of cellulase, hemicellulase, pectinase, amylase and pullulanase; and

treating at a temperature of 30 to 60° C., for 1 to 72 hours.

4. The purified hydroxymethylfurfural derivative of claim 1 is represented by the following general formula:

5. The purified hydroxymethylfurfural derivative of claim 4 being a purified R or S form optical isomer of the flowing formulae:

Assignments (2)
CHANGE OF NAME Recorded Jul 9, 2019
From: AMINO UP CHEMICAL CO., LTD.
To: AMINO UP CO., LTD.
Reel/Frame 049707/0144 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 18, 2014
From: NISHIOKA, HIROSHI; ITO, TOMOHIRO; MAEDA, TAKAHIRO
To: AMINO UP CHEMICAL CO., LTD.
Reel/Frame 033124/0116 →
Priority Claims (1)
JP 2011-277926 · Dec 20, 2011 · national
Continuity (1)
Related Publication 20150111943A1 · Apr 23, 2015