Silicone composition, release paper or film, and making method
An addition curing silicone composition comprising (A) an organopolysiloxane containing at least two alkenyl groups, (B) an adhesion promoter, (C) an organohydrogenpolysiloxane, and (D) a platinum catalyst is suited for use in release paper or film. The adhesion promoter is a compound which contains per molecule at least one substituent group having a functional group capable of radical reaction upon exposure to heat and/or UV, and at least one substituent group having a group capable of reaction with alkenyl and/or SiH group.
1. An addition curing silicone composition for release paper or film, comprising
(A) 100 parts by weight of organopolysiloxane containing at least two alkenyl groups in a molecule and having a viscosity of at least 0.04 Pa-s at 25° C.,
(B) 0.1 to 10 parts by weight of an adhesion promoter compound having the following formula:
(C) 0.1 to 20 parts by weight of an organohydrogenpolysiloxane containing at least three silicon-bonded hydrogen atoms in a molecule,
(D) a catalytic amount of a platinum group metal base catalyst, and
(E) an amount of an optional organic solvent.
2. A method for preparing a release paper or film, comprising the steps of
coating the silicone composition of claim 1 directly onto a paper or plastic film substrate, and
applying heat and/or UV radiation to cure the coating.
3. The method of claim 2 , wherein the step of applying heat and/or UV radiation comprises UV irradiation followed by heating to cure the coating.
4. A release paper or film comprising a cured coating of a silicone composition comprising
(A) 100 parts by weight of an organopolysiloxane containing at least two alkenyl groups in a molecule and having a viscosity of at least 0.04 Pa-s at 25° C.,
(B) 0.1 to 10 parts by weight of an adhesion promoter compound having the following formula:
(C) 0.1 to 20 parts by weight of an organohydrogenpolysiloxane containing at least three silicon-bonded hydrogen atoms in a molecule,
(D) a catalytic amount of a platinum group metal base catalyst, and
(E) an amount of an optional organic solvent.
5. The silicone composition of claim 1 , wherein component (A) is an organopolysiloxane of formula (8):
wherein
R 7 is alkenyl,
R 8 is a monovalent organic group free of aliphatic unsaturation or a hydroxyl group,
X 1 is a group of formula (9):
wherein b3, c3, d3, and e3 may be 0, provided that a3, b3, c3, d3, and e3 are such positive numbers that the organopolysiloxane has a viscosity of at least 0.04 Pa-s at 25° C. and a viscosity in 30 wt % toluene solution of up to 70 Pa-s at 25° C., and
α and β each are 0 or an integer of 1 to 3.
6. The silicone composition of claim 1 , wherein component (C) has the average compositional formula (10):
R 8 f H g SiO ( 4-f-g)/2 (10)
wherein R 8 is a monovalent organic group free of aliphatic unsaturation or a hydroxyl group, f is 0 to 3, g is more than 0 to 3, and f+g is a positive number of 1 to 3.
7. The silicone composition of claim 1 , wherein component (D) is a member selected from the group consisting of platinum black, chloroplatinic acid, chloroplatinic acid-olefin complexes, chloroplatinic acid-alcohol coordination compounds, rhodium, and rhodium-olefin complexes.
8. The silicone composition of claim 1 , which contains a solvent selected from the group consisting of toluene, xylene, ethyl acetate, acetone, methyl ethyl ketone, and hexane.