Curable fiberglass binder
A curable formaldehyde-free binding composition for use with fiberglass is provided. Such curable composition comprises an addition product of an amine and a reactant to form an amino-amide intermediate. To the amino-amide is added an aldehyde or ketone to form the curable binder composition. The composition when applied to fiberglass is cured to form a water-insoluble binder which exhibits good adhesion to glass. In a preferred embodiment the fiberglass is in the form of building insulation. In other embodiments the product is a microglass-based substrate for use in a printed circuit board, battery separator, filter stock, or reinforcement scrim.
1. A curable composition for use in the binding of fiberglass comprising an aldehyde or ketone and an amino-amide; wherein:
the amino-amide consists of the addition product of an aqueous solution of 1,6-hexanediamine and a reactant that are reacted at a temperature ranging from 120° C. to 150° C.,
the amino-amide is a, dimer, trimer, or tetramer, and
the reactant is selected from the group consisting of saturated or unsaturated anhydrides, carboxylic acids, esters, and salts and mixtures thereof.
2. A curable composition for use in the binding of fiberglass according to claim 1 , wherein said reactant is selected from the group consisting of maleic acid, fumaric acid, itaconic acid, itaconic anhydride, maleic anhydride, mono- and di-esters of maleic acid, mono- and di-esters of fumaric acid, and salts and mixtures thereof.
3. A curable composition for use in the binding of fiberglass according to claim 1 , wherein said reactant is maleic anhydride.
4. The curable composition of claim 1 , wherein an aldehyde is used with the amino-amide.
5. The curable composition of claim 4 , wherein the aldehyde is a reducing sugar.
6. The curable composition of claim 4 , wherein the aldehyde is a reducing monosaccharide.
7. The curable composition of claim 6 , wherein the aldehyde is glucose.
8. A curable composition for the binding of fiberglass according to claim 1 , further comprising at least one component selected from the group consisting of adhesion promoters, oxygen scavengers, moisture repellants, solvents, emulsifiers, pigments, fillers, anti-migration aids, coalescent aids, wetting agents, biocides, plasticizers, organosilanes, anti-foaming agents, colorants, waxes, suspending agents, anti-oxidants, and crosslinking catalysts.
9. A curable composition for use in the binding of fiberglass according to claim 1 , wherein the molar ratio of the amino-amide to the aldehyde or ketone is in the range from 1:3 to 1:10.
10. A curable composition for use in the binding of fiberglass comprising an aldehyde or ketone and an amino-amide, wherein:
the amino-amide comprises a dimer, trimer, or tetramer of an addition product of an aqueous solution of 1,6-hexanediamine and a reactant that are reacted at a temperature ranging from 120° C. to 150° C., and
the reactant is selected from the group consisting of saturated or unsaturated anhydrides, carboxylic acids, esters, and salts and mixtures thereof.
11. The curable composition of claim 10 , wherein the aldehyde or ketone comprises a reducing sugar.
12. The curable composition of claim 11 , wherein the reducing sugar comprises dextrose.
13. The curable composition of claim 10 , wherein the aldehyde or ketone comprises glyoxal.
14. The curable composition of claim 10 , wherein the reactant comprises an unsaturated anhydride.
15. The curable composition of claim 14 , wherein the unsaturated anhydride comprises maleic anhydride.
16. The curable composition of claim 14 , wherein the unsaturated anhydride comprises phthalic anhydride.
17. The curable composition of claim 14 , wherein the unsaturated anhydride comprises tetrahydro phthalic anhydride.
18. The curable composition of claim 10 , wherein the curable composition comprises at least one additional component selected from the group consisting of adhesion promoters, oxygen scavengers, moisture repellants, solvents, emulsifiers, pigments, fillers, anti-migration aids, coalescent aids, wetting agents, biocides, plasticizers, organosilanes, anti-foaming agents, colorants, waxes, suspending agents, anti-oxidants, and crosslinking catalysts.
19. The curable composition of claim 10 , wherein the curable composition comprises an additional crosslinker selected from the group consisting of a polycarboxylic acid and a polyvinyl alcohol.