Porous multi-component material for the capture and separation of species of interest
A method and porous multi-component material for the capture, separation or chemical reaction of a species of interest is disclosed. The porous multi-component material includes a substrate and a composite thin film. The composite thin film is formed by combining a porous polymer with a nanostructured material. The nanostructured material may include a surface chemistry for the capture of chemicals or particles. The composite thin film is coupled to the support or device surface. The method and material provides a simple, fast, and chemically and physically benign way to integrate nanostructured materials into devices while preserving their chemical activity.
1. A composite material for capture and concentration of a species of interest, comprising:
a. a substrate;
b. a porous composite thin film formed by mixing a porous polymer with a nanostructured material, wherein the porous polymer is present in a range from 5 wt % to about 40 wt % based on the weight of the porous composite thin film, wherein the porous polymer includes strands randomly dispersed within the nanostructured material and binding the nanostructured material, and the substrate is coated by the porous composite thin film, wherein the species of interest is captured and concentrated in the porous composite thin film for trace level detection in air or aqueous environments;
wherein the porous polymer is one of the following: polydimethylsiloxane (PDMS), polytetrafluoroethylene (PTFE), hydroxypropyl cellulose (HPC), sulfonated tetrafluoroethylene, and polyamide;
wherein the nanostructured material comprises a network of a plurality of nanoporous particles wherein each nanoporous particle comprises nanoporous silica, nanofiber silica, mesoporous silica, composites of mesoporous silica, carbon nanotube, metal-organic framework (MOF), graphene, high surface area polymer, a ceramic, mesoporous carbon, activated carbon, a metal oxide, a metal or any combinations thereof; and
c. surface chemistry on the nanostructured particle, wherein the surface chemistry is chemically functionalized prior to inclusion to the porous composite thin film.
2. The composite material of claim 1 wherein a thickness of the porous composite thin film is in a range of about 0.1 μm to about 100 μm.
3. The composite material of claim 1 wherein the substrate comprises one of the following: a fiber, a ceramic, a glass, a bead, stainless steel, leather, rubber, wood a metal wire, a planar surface, flexible silica coated wire, a cloth material, a fiber mesh, a porous media, a filter, a tubular structure, a sensor surface, and combinations thereof.
4. The composite material of claim 1 wherein the surface chemistry on the nanoporous particle forms a chemically reactive layer.
5. The composite material of claim 4 wherein the chemically reactive layer is at least one of the following: a sorbent layer, a silane, a physisorbed low vapor pressure organic, and a chemically ionic or covalent bound surface chemistry.
6. The composite material of claim 5 wherein the sorbent layer comprises a multifunctional chemistry, wherein the multifunctional chemistry is at least one of the following: organics, organometallics, metals, nanoparticles, complex molecules, and combinations thereof.
7. The composite material of claim 1 wherein the species of interest is in a gas-phase or a liquid-phase.
8. The composite material of claim 7 wherein the gas or liquid-phase species is at least one of the following: an explosive, an explosive variant, a chemical weapons agent, a pesticide, a drug, a volatile organic compound (VOC), a semi-volatile compound, a precious metal, a toxic metal, a rare earth element, and a radionuclide.
9. The composite material of claim 1 wherein the thin film bound to the substrate is integrated into commercially available equipment that directly interfaces with analytical testing equipment for testing, wherein the equipment is at least one of the following: a gas chromatographer (GC), a mass spectrometer, a gas chromatography coupled to a mass spectrometer (GC-MS), an ion mobility spectrometer (IMS), and a spectrometer using x-rays and photons in the UV-IR range.
10. The composite material of claim 1 wherein the porous composite thin film is coated onto the substrate via clip coating, spin coating, drop coating, or spray-on.