IP Library › Granted Patent US 9,381,502
Granted Patent B2
US 9,381,502 · App. 14/845,680 · Granted Jul 5, 2016

FCC catalyst, its preparation and use

Inventors: Dennis Stamires (Newport Beach, CA); Paul O'Connor (Hoevelaken, NL); Erik Jeroen LaHeij (Amstelveen, NL); Charles Vadovic (Houston, TX)
Assignee: Albemarle Netherlands, B.V.
B01J29/084B01D53/94B01J29/06B01J37/0045C01B3/02C10G1/086C10G2/33C10G11/05C10G29/205C10G35/06C10G49/08B01J35/002B01J2229/42C01B2203/1041
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Quick Facts
Patent No.
US 9,381,502
App. No.
14/845,680
Granted
Jul 5, 2016
Kind
B2
Abstract

Process for the preparation of a catalyst comprising the steps of (a) preparing a slurry comprising clay, zeolite, a sodium-free silica source, quasi-crystalline boehmite, and micro-crystalline boehmite, provided that the slurry does not comprise peptized quasi-crystalline boehmite, (b) adding a monovalent acid to the slurry, (c) adjusting the pH of the slurry to a value above 3, and (d) shaping the slurry to form particles. This process results in attrition resistant catalysts with a good accessibility.

Claims (11)

1. A process for the preparation of a catalyst comprising the steps of:

a) preparing a slurry comprising 5 to 70 wt % clay with less than 0.1 wt % Na 2 O, 10 to 70 wt % zeolite, 1 to 35 wt % a sodium-free silica source, 1 to 50 wt % non-peptised quasi-crystalline boehmite having a (020) reflection with a full width at half height (FWHH) of 1.5° or greater than 1.5° 2θ, and 1 to 50 wt % micro-crystalline boehmite having a (020) reflection with a full width at half height (FWHH) of smaller than 1.5° 2θ , provided that the slurry does not comprise peptised quasi-crystalline boehmite, wherein the solids content of the slurry is between 10 and 30 wt %,

b) adding a monovalent acid to the slurry sufficient to obtain a pH lower than 7,

c) adjusting the pH of the slurry to a value above 3, and

d) spray drying the slurry to form particles wherein the inlet temperature of the spray dryer is between 300 to 600° C. and the outlet temperature is between about 105 to 200° C.

2. The process of claim 1 , wherein the slurry contains 5 to 50 wt % of quasi-crystalline boehmite, and 1 to 20 wt % of micro-crystalline boehmite.

3. The process of claim 1 , wherein the slurry contains 15 to 35 wt % zeolite, 10 to 50 wt % clay and 4 to 18 wt % sodium-free silicon source.

4. The process of claim 1 , wherein at step c) the pH is adjusted to between 2 and 5.

5. A catalyst composition comprising clay, zeolite, a sodium-free silica source, quasi and micro-crystalline boehmite, wherein the composition is prepared by the process of claim 1 .

6. The composition of claim 5 , wherein the catalyst comprises 1-50 wt % of quasi-crystalline boehmite, 1 to 25 wt % of micro-crystalline boehmite, 1 to 25 wt % silica, 5 to 50 wt % zeolite, and the balance clay, calculated as oxides.

7. The composition of claim 6 , wherein the catalyst comprises 3-40 wt % of quasi-crystalline boehmite, and 5-25 wt % of micro-crystalline boehmite.

Assignments (2)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 4, 2024
From: ALBEMARLE NETHERLANDS B.V.
To: KETJEN NETHERLANDS B.V.
Reel/Frame 067009/0230 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 8, 2016
From: LAHEIJ, ERIK JEROEN; O'CONNOR, PAUL; STAMIRES, DENNIS; VADOVIC, CHARLES
To: ALBEMARLE NETHERLANDS B.V.
Reel/Frame 038839/0974 →
Priority Claims (1)
EP 05075577 · Mar 9, 2005 · regional
Continuity (4)
Continuation 13828268 · Mar 14, 2013
Continuation 11722388
Provisional Application 60637457 · Dec 21, 2004
Related Publication 20150375216A1 · Dec 31, 2015