Method for producing anhydrosugar alcohol through continuous dehydration reaction of hydrogenated sugar
The present invention relates to a method for producing an anhydrosugar alcohol and, more specifically, to a method for producing an anhydrosugar alcohol which, when the step of subjecting a hydrogenated sugar to a dehydration reaction in a reactor so as to convert same to an anhydrosugar alcohol is performed, allows the hydrogenated sugar to be continuously introduced into the reactor and the produced anhydrosugar alcohol to be continuously discharged out of the reactor while the dehydration reaction is carried out, also prevents a reaction mixture from circulating inside and outside the reactor while the dehydration reaction is carried out, and thereby can significantly improve production efficiency compared with a conventional process adopting a batch or semi-batch-type dehydration reaction and thus can be appropriately applied particularly to a large-scale anhydrosugar alcohol production process.
1. A method for producing anhydrosugar alcohol comprising the step of converting hydrogenated sugar to anhydrosugar alcohol by dehydration reaction in a reactor, wherein while the dehydration reaction is conducted, the hydrogenated sugar is continuously fed into the reactor and the produced anhydrosugar alcohol is continuously discharged out of the reactor, and the reaction mixture is not circulated in and out of the reactor during the conduction of the dehydration reaction.
2. The method for producing anhydrosugar alcohol according to claim 1 , wherein while the dehydration reaction of the hydrogenated sugar is conducted, a continuous flow by the reaction mixture is formed within the reactor.
3. The method for producing anhydrosugar alcohol according to claim 2 , wherein the continuous flow is steady state flow.
4. The method for producing anhydrosugar alcohol according to claim 1 , wherein the feeding rate of the hydrogenated sugar into the reactor is 0.95 to 1.05 times the discharge rate of the anhydrosugar alcohol out of the reactor.
5. The method for producing anhydrosugar alcohol according to claim 1 , wherein the dehydration reaction of the hydrogenated sugar is conducted in a single reactor, or by using a facility wherein two or more reactors are serially connected.
6. The method for producing anhydrosugar alcohol according to claim 5 , wherein the dehydration reaction of the hydrogenated sugar is conducted by using a facility wherein two or more reactors are serially connected, and during the dehydration reaction, a continuous flow by the reaction mixture is formed and maintained throughout the whole reactors.
7. The method for producing anhydrosugar alcohol according to claim 1 , wherein an acid catalyst is used in the step of converting hydrogenated sugar to anhydrosugar alcohol by dehydration reaction.
8. The method for producing anhydrosugar alcohol according to claim 7 , wherein the acid catalyst is a single acid catalyst selected from sulfuric acid, nitric acid, hydrochloric acid, p-toluenesulfonic acid and phosphoric acid; or the acid catalyst is an acid mixture of a first acid and a second acid wherein the first acid is sulfuric acid and the second acid is one or more sulfur-containing acid materials selected from the group consisting of p-toluenesulfonic acid, methanesulfonic acid, ethanesulfonic acid, benzenesulfonic acid, naphthalenesulfonic acid and aluminum sulfate.
9. The method for producing anhydrosugar alcohol according to claim 1 , further comprising neutralization of the resulting liquid of the dehydration reaction of hydrogenated sugar.
10. The method for producing anhydrosugar alcohol according to claim 9 , further comprising distillation of the neutralized resulting liquid of the dehydration reaction of hydrogenated sugar after removal of moisture therefrom.
11. The method for producing anhydrosugar alcohol according to claim 10 , wherein the distillation is conducted by using a thin-film evaporator.
12. The method for producing anhydrosugar alcohol according to claim 10 , further comprising purification of the resulting liquid of distillation by one or more procedures selected from crystallization, decolorization and treatment with ion exchange resin.