Light emitting device and method of manufacturing thereof
A light emitting device includes a package having side walls which define a recess, a light emitting element arranged in the recess, and a sealing member which seals the light emitting element. The sealing member includes a first portion which contains a fluorescent material and covers the light emitting element, and a second portion which does not contain a fluorescent material and is arranged over the first portion. The fluorescent material is a fluoride fluorescent material activated with tetravalent manganese represented by the following formula (I). The particles of the fluorescent material has a surface region with a tetravalent manganese ion concentration is lower than inner side. A 2 [M 1-b Mn 4+ b F 6 ] (I) In the formula (I), A is a cation which contains K+ and may contain at least one selected from the group consisting of Li + , Na + , Rb + , Cs + , and NH 4 + , M is at least one of 15 Group 4 and Group 14 elements, and 0<b<0.2.
1. A light emitting device comprising:
a package having side walls which define a recess;
a light emitting element arranged in the recess; and
a sealing member which seals the light emitting element;
wherein the sealing member comprises:
a first sealing member portion covering the light emitting element, the first sealing member portion comprising a first binder portion, and fluorescent material particles located in the first binder portion, and
a second sealing member portion covering the first sealing member portion, the second sealing member portion comprising a second binder portion, and substantially no fluorescent material particles located in the second binder portion,
wherein the fluorescent material particles include particles of a fluoride fluorescent material that is activated with tetravalent manganese ions and has a chemical composition represented by the following formula (I),
A 2 [M 1-b Mn 4+ b F 6 ] (I)
wherein A is a cation which contains at least K + and may further contain at least one selected from the group consisting of Li + , Na + , Rb + , Cs + , and NH 4 + , M is at least one element selected from the group consisting of Group 4 elements and Group 14 elements, and 0<b<0.2, and
wherein the particles of fluoride fluorescent material include a surface region and an inner region, both the surface region and the inner region comprising tetravalent manganese ions, and
wherein a tetravalent manganese ion concentration of the surface region of the particles of fluoride fluorescent material is lower than a tetravalent manganese ion concentration of the inner region of the particles of fluoride fluorescent material.
2. The light emitting device according to claim 1 , wherein a thickness of the second sealing member portion directly above the light emitting element is one tenth or greater with respect to an entire thickness of the sealing member.
3. The light emitting device according to claim 1 , wherein a thickness of the second sealing member portion directly above the light emitting element is one forth or greater with respect to an entire thickness of the sealing member.
4. The light emitting device according to claim 1 , wherein the sealing member includes a resin, and a content of the fluorescent material is 10 to 200 parts by mass with respect to 100 parts by mass of the resin, and a content of the fluorescent material in the first sealing member portion is 20 to 400 parts by mass with respect to the resin contained in the first sealing member portion.
5. The light emitting device according to claim 1 , wherein M in the formula (I) is at least one element selected from the group consisting of titanium (Ti), zirconium (Zr), hafnium (Hf), silicon (Si), germanium (Ge), and tin (Sn).
6. The light emitting device according to claim 1 , wherein the light emitting element is to emit light which has an emission peak wavelength in a range of 380 nm to 485 nm.
7. The light emitting device according to claim 1 , wherein the fluorescent material further includes a fluorescent material to absorb light in a wavelength range of 380 nm to 485 nm and emit green to yellow light which has an emission peak wavelength in a range of 495 nm to 590 nm.
8. The light emitting device according to claim 7 , wherein the fluorescent material to emit light of green to yellow color includes a β-sialon fluorescent material represented by a composition formula of (Si,Al) 6 (O,N) 8 :Eu, a thiogallate fluorescent material represented by a composition formula of SrGa 2 S 4 :Eu, a halosilicate fluorescent material represented by a composition formula of (Ca,Sr,Ba,Zn) 8 MgSi 4 O 16 (F,Cl,Br,I) 2 :Eu, or a rare earth aluminate fluorescent material represented by a composition formula (Y,Lu) 3 (Al,Ga) 5 O 12 :Ce.
9. The light emitting device according to claim 7 , wherein a mass ratio of the fluorescent material to emit green to yellow light to the fluoride fluorescent material is 5:95 to 95:5.
10. An image display device comprising at least one light emitting device according to claim 1 .
11. The light emitting device according to claim 1 , wherein a material of the first binder portion is the same as a material of the second binder portion.