IP Library Granted Patent US 9,434,616
Granted Patent B2
US 9,434,616 · App. 14/067,672 · Granted Sep 6, 2016

Sodium hypochlorite composition and method of storing and transporting sodium hypochlorite

Inventors: David W. Cawlfield (Athens, TN); Randall Taylor Morris (Benton, TN); Richard Carl Ness (Cleveland, TN); Leonard L. Scott (Daphne, AL); Sanders Harrison Moore (Ooltewah, TN); Awuri Priye Asuru (Cleveland, TN)
Assignee: OLIN CORPORATION
C01B11/062C01B11/068
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Quick Facts
Patent No.
US 9,434,616
App. No.
14/067,672
Granted
Sep 6, 2016
Kind
B2
Abstract

A sodium hypochlorite composition comprising between about 25% and about 40% sodium hypochlorite, in the form of a slurry of sodium hypochlorite pentahydrate crystals in a mother liquor saturated in sodium hypochlorite. The composition can include sodium chloride, and an alkai stabilizer such as sodium hydroxide and sodium carbonate. The slurry is preferably between about −15° C. and about 10° C. A method of transporting or storing sodium hypochlorite is also provided in which the sodium hypochlorite is in the form of a slurry of sodium hypochlorite pentahydrate crystals in a mother liquor saturated in sodium hypochlorite. The composition can include sodium chloride, and an alkali stabilizer such as sodium hydroxide and sodium carbonate. The slurry is preferably between about −15° C. and about 10° C.

Claims (13)

1. A sodium hypochlorite composition comprising sodium hypochlorite pentahydrate crystals and a mother liquor saturated in sodium hypochlorite, comprising between about 25% and about 40% by weight sodium hypochlorite, and sodium chloride, in amount between at least 3.5% and about 10% by weight.

2. The composition according to claim 1 further comprising an alkali to stabilize the composition.

3. The composition according to claim 2 , wherein the alkali is at least one of sodium hydroxide and sodium carbonate.

4. The composition according to claim 3 wherein the alkali comprises between about 0.01% and about to 3% by weight of the composition.

5. The composition according to claim 1 , wherein the size (longest dimension) of the sodium hypochlorite pentahydrate crystals is less than about 1 mm.

6. The composition according to claim 5 , wherein the size (longest dimension) of the sodium hypochlorite pentahydrate crystals is less than about 0.5 mm.

7. The composition according to claim 6 , wherein the size (longest dimension) of the sodium hypochlorite pentahydrate crystals is less than about 0.1 mm.

8. The composition according to claim 6 , wherein the size of the sodium hypochlorite pentahydrate crystals is sufficiently small to maintain a suitable viscosity.

9. The composition according to claim 1 wherein the average length to diameter ratio of the sodium hypochlorite pentahydrate crystals is less than about 20:1.

10. The composition according to claim 9 wherein the average length to diameter ratio of the sodium hypochlorite pentahydrate crystals is less than about 6:1.

11. The composition according to claim 1 wherein the composition is at a temperature of between about −15° C. and about 10° C.

12. The composition according to claim 11 wherein the composition is at a temperature of between about −10° C. and about +5° C.

13. The composition according to claim 1 wherein the sodium chloride composition is at least 7%.

Assignments (4)
SECURITY INTEREST Recorded May 19, 2026
From: OLIN CORPORATION; OLIN WINCHESTER, LLC
To: BANK OF AMERICA, N.A., AS ADMINISTRATIVE AGENT AND COLLATERAL MAY 19, 2026
Reel/Frame 074694/0881 →
RELEASE OF SECURITY INTEREST Recorded Jul 29, 2021
From: BANK OF AMERICA, N.A.
To: OLIN CORPORATION
Reel/Frame 057016/0561 →
SECURITY AGREEMENT Recorded Aug 7, 2020
From: OLIN CORPORATION
To: BANK OF AMERICA, N.A.
Reel/Frame 053436/0262 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 7, 2014
From: CAWLFIELD, DAVID W.; MORRIS, RANDALL TAYLOR; NESS, RICHARD CARL; SCOTT, LEONARD L.; MOORE, SANDERS HARRISON; ASURU, AWURI PRIYE
To: OLIN CORPORATION
Reel/Frame 032837/0971 →
Continuity (2)
Provisional Application 61720464 · Oct 31, 2012
Related Publication 20140117278A1 · May 1, 2014