IP Library Granted Patent US 9,446,983
Granted Patent B2
US 9,446,983 · App. 13/756,603 · Granted Sep 20, 2016

Glass compositions and fibers made therefrom

Inventors: Hong Li (Sewickley, PA); James C. Watson (Lake Wylie, SC)
Assignee: PPG Industries Ohio, Inc.
C03C13/00C03C13/06C08J5/043D03D15/0011D04H13/008Y10T442/2992Y10T442/30Y10T442/60
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Quick Facts
Patent No.
US 9,446,983
App. No.
13/756,603
Granted
Sep 20, 2016
Kind
B2
Abstract

Some embodiments of the present invention provide fiberizable glass compositions formed from batch compositions comprising amounts of one or more glassy minerals, including perlite and/or pumice. Some embodiments of the present invention related to glass fibers formed from such batch compositions, and composites and other materials incorporating such glass fibers.

Claims (38)

1. A plurality of glass fibers, wherein each glass fiber comprises:

53 to less than 62 weight percent SiO 2 ;

8-12 weight percent Al 2 O 3 ;

0-3 weight percent ZnO;

greater than 0 to 3 weight percent TiO 2 ;

8.5-18 weight percent alkali metal oxide (R 2 O) component;

a metal oxide (RO) component selected from the group consisting of MgO, CaO, SrO, BaO, and ZnO, wherein the metal oxide component is present in an amount to provide a mass ratio of R 2 O/RO ranging from about 0.28 to about 1.7; and

less than 1 weight percent of Fe 2 O 3 .

2. The plurality of glass fibers of claim 1 , wherein the glass fibers have a length of less than about 105 millimeters.

3. The plurality of glass fibers of claim 1 , wherein the glass fibers have a length of less than about 13 millimeters.

4. The plurality of glass fibers of claim 1 , wherein the glass fibers have a length of greater than about three millimeters.

5. The plurality of glass fibers of claim 1 , wherein the glass fibers have a length of greater than about fifty millimeters.

6. A fiber glass strand comprising the plurality of glass fibers of claim 1 .

7. A roving comprising the plurality of glass fibers of claim 1 .

8. A yarn comprising the plurality of glass fibers of claim 1 .

9. A woven fabric comprising the plurality of glass fibers of claim 1 .

10. A non-woven fabric comprising the plurality of glass fibers of claim 1 .

11. The plurality of glass fibers of claim 1 , wherein each glass fiber comprises 0-3 weight percent MnO 2 .

12. A polymeric composite comprising:

a polymeric material; and

the plurality of glass fibers of claim 1 .

13. The polymeric composite of claim 12 , wherein the plurality of glass fibers have a length of less than about 105 millimeters.

14. The polymeric composite of claim 12 , wherein the plurality of glass fibers have a length of less than about 13 millimeters.

15. The polymeric composite of claim 12 , wherein the plurality of glass fibers have a length of greater than about fifty microns.

16. The polymeric composite of claim 12 , wherein the plurality of glass fibers have a length of greater than about fifty millimeters.

17. The polymeric composite of claim 12 , wherein the plurality of glass fibers are in the form of a non-woven fabric.

18. The polymeric composite of claim 12 , wherein the plurality of glass fibers are in the form of a woven fabric.

19. The polymeric composite of claim 12 , wherein the polymeric material comprises a thermoplastic polymer.

20. The polymeric composite of claim 12 , wherein the polymeric material comprises a thermosetting polymer.

21. A roofing product comprising the plurality of glass fibers of claim 1 .

22. A plurality of glass fibers, wherein each glass fiber comprises:

53-64 weight percent SiO 2 ;

greater than 10 to 14 weight percent Al 2 O 3 ;

0-3 weight percent ZnO;

greater than 0 to 3 weight percent TiO 2 ;

10-18 weight percent alkali metal oxide (R 2 O) component;

a metal oxide (RO) component selected from the group consisting of MgO, CaO, SrO, BaO, and ZnO, wherein the metal oxide component is present in an amount to provide a mass ratio of R 2 O/RO ranging from about 0.38 to about 1.7; and

less than 1 weight percent of Fe 2 O 3 .

Assignments (3)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 7, 2020
From: NIPPON ELECTRIC GLASS AMERICA, INC.
To: ELECTRIC GLASS FIBER AMERICA, LLC
Reel/Frame 051843/0666 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 28, 2020
From: PPG INDUSTRIES OHIO, INC.
To: NIPPON ELECTRIC GLASS AMERICA, INC.
Reel/Frame 051724/0323 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 1, 2013
From: LI, HONG; WATSON, JAMES C.
To: PPG INDUSTRIES OHIO, INC.
Reel/Frame 030121/0172 →
Continuity (4)
Continuation In Part 13365590 · Feb 3, 2012
Continuation In Part 12534490 · Aug 3, 2009
Provisional Application 61594426 · Feb 3, 2012
Related Publication 20130143459A1 · Jun 6, 2013