System and method for pre-treatment of rubber-modified asphalt cement, and emulsions thereof
This invention encompasses asphalt cement emulsions, as well as methods for preparing a pre-treated rubber-modified asphalt cement emulsions and methods for coating industrial surfaces using asphalt cement emulsions.
1. A method for preparing an asphalt cement emulsion, comprising:
a) providing a rubber-modified asphalt cement; followed by
b) preparing a pre-treatment mixture comprising:
i) the rubber-modified asphalt cement; and
ii) one or more emulsifiers comprising an amine compound; and
c) mixing the pre-treatment mixture with an emulsification solution comprising: water and clay.
2. The method of claim 1 , wherein the asphalt cement emulsion comprises from about 0.01 to 25 wt. % of the rubber-modified asphalt cement.
3. The method of claim 1 , wherein the clay is a hydrophobic clay.
4. The method of claim 1 , wherein the clay is sepiolite clay.
5. The method of claim 1 , wherein the one or more emulsifiers comprises at least about 20 wt. % of the amine compound.
6. The method of claim 1 , wherein the one or more emulsifiers comprises at least about 40 wt. % of the amine compound.
7. The method of claim 1 , wherein the pre-treatment mixture is readily-emulsifiable.
8. The method of claim 1 , wherein less than about 0.5 wt. % of the emulsion, relative to the total weight of the emulsion, remains on a 850-μm mesh sieve following contact of the sieve with the emulsion during the Sieve Emulsion Test.
9. The method of claim 1 , wherein the emulsion is curable to form a cured coating having a softening point of greater than about 350° F.
10. The method of claim 9 , wherein less than 5 wt. % loss of the cured coating occurs during the Wet Track Abrasion Test, relative to the total weight of the cured coating.
11. The method of claim 1 , wherein preparing the pre-treatment mixture comprises: heating a mixture of the rubber-modified asphalt cement and the one or more emulsifiers to a temperature in the range of 300° F. to 400° F.
12. The method of claim 11 , wherein the pre-treatment mixture has a reduced softening point relative to the rubber-modified asphalt cement.
13. The method of claim 12 , wherein the softening point of the pretreatment mixture is in the range of 110° F. to 120° F.
14. The method of claim 12 , wherein the the pre-treatment mixture has a softening point reduced by at least about 8% relative to the rubber-modified asphalt cement.
15. The method of claim 11 , wherein the pre-treatment mixture is more readily emulsified than the rubber-modified asphalt cement.
16. The method of claim 1 , wherein the pre-treatment mixture has a reduced softening point relative to the rubber-modified asphalt cement.
17. The method of claim 1 , wherein the pre-treatment mixture is more readily emulsified than the rubber-modified asphalt cement.