Copolymer of ethylene and alpha-olefin, and method for preparing same
A liquid random copolymer of ethylene and alpha-olefin prepared by using specific metallocene catalyst and ionic compound and a method for preparing the same are disclosed. The liquid random copolymer has high viscosity index and shear stability so that it is useful as synthetic lubricants. The liquid random copolymer of ethylene and alpha-olefin (1) comprises 60 to 40 mol % of ethylene units and 40 to 60 mol % of alpha-olefin unit having 3 to 20 carbon atoms, (2) has number average molecular weight (Mn) of 500 to 10,000 and a molecular weight distribution (Mw/Mn, Mw is the weight average molecular weight) of 3 or less measured by Gel Permeation Chromatography (GPC) (3) has Kinematic Viscosity at 100° C. of 30 to 5,000, (4) has pour point of 30 to −45° C., and (5) has Bromine Number of 0.1 or less.
1. A method for preparing a liquid random copolymer of ethylene and alpha-olefin, comprising a step of:
carrying out solution polymerization of ethylene and alpha-olefin having 3 to 20 carbon atoms, under a catalyst system containing:
(A) a bridged metallocene compound represented by following Formula 1, and
(B) at least one compound selected from a group consisting of (i) an organoaluminum oxy-compound and (ii) a compound which reacts with the bridged metallocene compound to form ion pair,
wherein, R 1 and R 4 are hydrogen atom; R 2 , R 3 , R 5 , R 8 , R 9 and R 12 are independently hydrogen atom, hydrocarbon group or silicon-containing hydrocarbon group, and adjacent groups can be connected to form a ring structure at least one of R 2 and R 3 is hydrocarbon group having 4 or more carbon atoms; R 6 and R 11 are the same as each other and are hydrogen atom, hydrocarbon group or silicon-containing hydrocarbon group R 7 and R 10 are the same as each other and are hydrogen atom, hydrocarbon group or silicon-containing hydrocarbon group; R 6 and R 7 can be connected to hydrocarbon having 2 to 3 carbon atoms to form a ring structure R 11 and R 10 can be connected to hydrocarbon having 2 to 3 carbon atoms to form a ring structure; R 6 , R 7 , R 10 and R 11 are not hydrogen atom at the same time; Y is carbon atom or silicon atom; R 13 and R 14 are independently aryl group; M is Ti, Zr or Hf; Q is independently halogen, hydrocarbon group, anionic ligands or a neutral ligand which can be coordinated to a lone pair of electrons; j is an integer of 1-4; and
wherein the liquid random copolymer (1) comprises 40 to 60 mol % of ethylene units and 60 to 40 mol % of alpha-olefin units having 3 to 20 carbon atoms; (2) has a number average molecular weight (Mn) of 500 to 10,000 and a molecular weight distribution (Mw/Mn wherein Mw is weight average molecular weight) of 3 or less measured by gel permeation chromatography (GPC); (3) has a kinematic viscosity at 100° C. of 30 to 5,000; (4) has a pour point of 30 to −45° C., and (5) has a bromine number of 0.1 or less.
2. The method as claimed in claim 1 , wherein R 6 and R 11 are same hydrocarbon group having 1 to 20 carbon atoms.
3. The method as claimed in claim 1 , wherein R 2 or R 3 is n-butyl group.
4. The method as claimed in claim 1 , wherein R 6 and R 11 are tert-butyl group.
5. The method as claimed in claim 1 , wherein the compound which reacts with the bridged metal is a compound represented by following Formula 6,
wherein Re+ is H + , carbenium cation, oxonium cation, ammonium cation, phosphonium cation, cycloheptyltrienyl cation, ferroceniun cation having transition metal; and R f to R i each is independently a hydrocarbon group having 1 to 20 carbon atoms.
6. The method as claimed in claim 5 , wherein the catalyst system further comprises organoaluminum compound selected from the group consisting of trimethyl aluminum and triisobutyl aluminum.