Cellulose acylate film, polarizing plate and liquid crystal display device
Provide a cellulose acylate film with small photoelastic coefficient, low moisture content and low haze, and a polarizing plate and a liquid crystal display device using the same. Also provided is a cellulose acylate film including at least cellulose acylate and a resin produced by hydrogenating a polymer containing a repeating unit derived from a monomer represented by the formula (1) below and hydroxyl group: in the formula (1), R 1 represents a hydrogen atom or C 1-5 alkyl group; each R 2 represents a hydrogen atom or substituent, at least one of (R 2 )s being a hydroxyl group-containing substituent; moiety (A) may form, or does not necessarily form, a five- or six-membered ring; n represents an integer of 1 to 5, and when n is 2 or larger, the plurality of (R 2 )s may be same with or different from each other.
1. A cellulose acylate film comprising at least a cellulose acylate and a resin produced by hydrogenating a polymer containing a repeating unit derived from a monomer represented by the formula (1) below and hydroxyl group:
in the formula (1), R 1 represents a hydrogen atom or C 1-5 alkyl group; each R 2 represents a hydrogen atom or substituent, at least one of (R 2 )s being a hydroxyl group-containing substituent; moiety (A) may form, or does not necessarily form, a five- or six-membered ring; n represents an integer of 1 to 5, and when n is 2 or larger, the plurality of (R 2 )s may be same with or different from each other,
wherein the cellulose acylate film has a photoelastic coefficient of 8.0×10 −12 Pa −1 or smaller, a haze of 0.5% or smaller, and a moisture content at 25° C. and 80% relative humidity of 5% or less, and
wherein the resin is obtained by reprecipitation in addition to removal of a catalyst on completion of the hydrogenation reaction of the polymer.
2. The cellulose acylate film of claim 1 , wherein the resin is a copolymer which contains one or more species of the repeating units represented by the formula (1), and contains repeating units derived from two or more different species of monomers.
3. The cellulose acylate film of claim 1 , comprising the repeating unit derived from a monomer represented by the formula (1), in which the unsaturated ethylenic bond in the moiety (A) does not link with the aromatic ring to thereby form no cyclic structure.
4. The cellulose acylate film of claim 1 , wherein R 1 represents a hydrogen atom or methyl group.
5. The cellulose acylate film of claim 1 , wherein the resin has a hydroxyl value of 10 to 200 mg/KOH/g.
6. The cellulose acylate film of claim 1 , wherein the resin has a weight-average molecular weight of 200 to 5,000.
7. The cellulose acylate film of claim 5 , wherein the resin has a weight-average molecular weight of 200 to 5,000.
8. The cellulose acylate film of claim 1 , wherein the cellulose acylate satisfies the degree of acyl substitution given by the equation below:
1.5≦A≦3.0
wherein A represents the degree of acyl substitution.
9. The cellulose acylate film of claim 5 , wherein the cellulose acylate satisfies the degree of acyl substitution given by the equation below:
1.5≦A≦3.0
wherein A represents the degree of acyl substitution.
10. The cellulose acylate film of claim 6 , wherein the cellulose acylate satisfies the degree of acyl substitution given by the equation below:
1.5≦A≦3.0
wherein A represents the degree of acyl substitution.
11. The cellulose acylate film of claim 1 , wherein the cellulose acylate satisfies the degree of acyl substitution given by the equation below:
1.5≦A≦3.0
wherein A represents the degree of acyl substitution.
12. The cellulose acylate film of claim 1 , wherein the cellulose acylate satisfies the degree of acetyl substitution given by the equation below:
2.0≦B≦3.0
wherein B represents the degree of acetyl substitution.
13. The cellulose acylate film of claim 5 , wherein the cellulose acylate satisfies the degree of acetyl substitution given by the equation below:
2.0≦B≦3.0
wherein B represents the degree of acetyl substitution.
14. The cellulose acylate film of claim 6 , wherein the cellulose acylate satisfies the degree of acetyl substitution given by the equation below:
2.0≦B≦3.0
wherein B represents the degree of acetyl substitution.
15. The cellulose acylate film of claim 1 , wherein the cellulose acylate satisfies the degree of acetyl substitution given by the equation below:
2.0≦B≦3.0
wherein B represents the degree of acetyl substitution.
16. A polarizing plate comprising at least a polarizer, and the cellulose acylate film of claim 1 .
17. A liquid crystal display device comprising at least a liquid crystal cell, and the polarizing plate of claim 16 .