White ink for ink-jet
View Patent ↗To provide an ink-jet white ink of active energy ray-curable type, wherein the white ink has high printing stability and good hiding property, and is particularly suitable for printing on the single-pass ink-jet printing system. An ink-jet white ink of active energy ray-curable type, comprising titanium oxide, a pigment dispersant, and a polymerizable compound, wherein the content of the titanium oxide is from 15 to 30% by weight with reference to the total weight of the ink, and wherein the weight average particle diameter of the titanium oxide is 180 to 250 nm. In an embodiment of the ink, the titanium oxide is titanium oxide that surface is treated with silica and the pigment dispersant comprises a basic dispersant.
1. An ink, comprising titanium oxide, a pigment dispersant, and a polymerizable compound,
wherein titanium oxide is present in the ink in an amount of from 15 to 30% by weight with reference to a total weight of the ink,
wherein a weight average particle diameter of the titanium oxide is from 180 to 250 nm, and
wherein the titanium oxide has, on a surface thereof, a surface-treating agent comprising:
at least one of an inorganic surface-treating agent selected from the group consisting of an aluminum compound, silica and zirconia; and
an organic surface-treating agent.
2. The ink of claim 1 , wherein the titanium oxide has hydroxyl groups on a treated surface thereof.
3. The ink of claim 1 , wherein the pigment dispersant comprises a basic dispersant.
4. The ink of claim 1 , wherein the polymerizable compound comprises at least one of the polymerizable compounds of formulae (1) and (2):
wherein R 1 and R 2 are each independently a hydrogen atom or a methyl group, R 3 is a hydrogen atom or an alkyl group with 1 to 10 carbon atoms, and n is an integer of 1 to 10,
wherein R 1 is a hydrogen atom or a methyl group, R 3 is a hydrogen atom or an alkyl group with 1 to 10 carbon atoms, and m is an integer of 1 to 10.
5. The ink of claim 1 , further comprising a polymerization initiator, wherein the polymerization initiator comprises at least one member selected from the group consisting of 2,4,6-trimethylbenzoyl diphenyl phosphine oxide, bis(2,4,6-trimethylbenzoyl)phenylphosphine oxide, and 4-benzoyl-4′-methyldiphenyl sulfide.
6. The ink of claim 1 , further comprising an organic solvent, which is present in an amount of from 0.01 to 5% by weight with reference to the total weight of the ink.
7. The ink of claim 1 , wherein the organic surface-treating agent is at least one member selected from the group consisting of a polyalcohol, an alkanolamine, and an organosilicon compound.
8. The ink of claim 1 , wherein the inorganic surface-treating agent comprises a combination of an aluminum compound and silica.
9. The ink of claim 1 , wherein the inorganic surface-treating agent comprises: i) a combination of aluminum hydroxide and silica; ii) a combination of alumina and silica; or iii) both a combination of aluminum hydroxide and silica and a combination of alumina and silica.
10. The ink of claim 1 , wherein the aluminum compound comprises aluminum hydroxide, alumina, or a combination thereof.
11. The ink of claim 1 , wherein a weight average particle diameter of the titanium oxide is from 200 to 250 nm.