Methods for purifying aluminium ions
There are provided processes for purifying aluminum ions. Such processes comprise precipitating the aluminum ions under the form of Al(OH) 3 at a first pH range; converting Al(OH) 3 into AlCl 3 by reacting Al(OH) 3 with HCl and precipitating said AlCl 3 ; and heating the AlCl 3 under conditions effective for converting AlCl 3 into Al 2 O 3 and optionally recovering gaseous HCl so-produced. The processes can also comprise converting alumina into aluminum.
1. A process for purifying aluminum ions comprising:
leaching an aluminum containing material chosen from an aluminum-containing ore, a recycled industrial aluminum-containing material, red mud, fly ashes, slag, alumina, aluminum hydroxide, aluminum chloride and aluminum metal with an acid so as to obtain a leachate comprising said aluminum ions and ions from at least one metal; and optionally a solid residue;
optionally separating the leachate from the solid residue;
precipitating said aluminum ions from said leachate in the form of Al(OH) 3 at a pH of about 7 to about 10 in order to obtain a solid comprising said Al(OH) 3 and a liquid comprising said ions from said at least one metal;
separating said solid from said liquid;
converting said Al(OH) 3 into AlCl 3 by reacting Al(OH) 3 with HCl and precipitating said AlCl 3 ;
recovering said AlCl 3 ; and
heating said AlCl 3 under conditions effective for converting AlCl 3 into Al 2 O 3 and optionally recovering gaseous HCl so-produced.
2. The process of claim 1 , wherein said pH is about 9 to about 10.
3. The process of claim 1 , wherein precipitation of said aluminum ions is carried out at a temperature of about 50 to about 75° C.
4. The process of claim 1 , wherein precipitating said aluminum ions in the form of Al(OH) 3 at a pH of about 7 to about 10 is carried out by reacting said aluminum ions with AlCl 3 .
5. The process of claim 1 , wherein a first precipitation of said aluminum ions in the form of Al(OH) 3 is carried out at said pH of about 7 to about 10 by reacting said aluminum ions with HCl and/or AlCl 3 and wherein a second precipitation of said aluminum ions in the form of Al(OH) 3 is carried out by reacting said aluminum ions with AlCl 3 in a reaction media maintained at a pH value of about 7 to about 9.
6. The process of claim 5 , wherein said second precipitation is carried out by maintaining pH at a value of about 7.5 to about 8.5.
7. The process of claim 1 , wherein converting said Al(OH) 3 into said AlCl 3 is carried out by reacting said Al(OH) 3 with said HCl, said HCl having a concentration of about 9 to about 10 moles per liter.
8. The process of claim 1 , wherein converting said Al(OH) 3 into said AlCl 3 is carried out by reacting said Al(OH) 3 with said HCl at a temperature of about 80 to about 120° C.
9. The process of claim 1 , wherein said obtained AlCl 3 is purified by means of an ion exchange resin.
10. The process of claim 1 , wherein said AlCl 3 is precipitated in the form of AlCl 3 .6H 2 O at a temperature of about 100 to about 120° C.
11. The process of claim 1 , wherein said AlCl 3 is precipitated in the form of AlCl 3 .6H 2 O, under vacuum, at a temperature of about 70 to about 90° C.
12. The process of claim 1 , wherein converting AlCl 3 into Al 2 O 3 is carried out by calcination.
13. The process of claim 12 , wherein said calcination is carried out by injecting steam.
14. The process of claim 13 , wherein steam is overheated steam.
15. The process of claim 1 , wherein said aluminum ions are obtained by:
leaching said aluminum-containing material with said acid so as to obtain a composition comprising said aluminum ions and other metal ions; and
at least substantially selectively removing said other metal ions or said aluminum ions from said composition by substantially selectively precipitating said other metal ions or said aluminum ions from said composition.
16. The process of claim 1 , wherein said aluminum-containing material is an aluminum-containing ore.
17. The process of claim 1 , wherein said aluminum-containing material is chosen from aluminosillicate minerals, clays, argillite, nepheline, mudstone, beryl, cryolite, garnet, spinel, kaolin, bauxite and mixtures thereof.
18. The process of claim 1 , wherein said aluminum-containing material is a recycled industrial aluminum-containing material.
19. The process of claim 1 , wherein said aluminum-containing material is red mud or fly ashes.
20. A process for purifying aluminum ions comprising:
leaching an aluminum containing material chosen from an aluminum-containing ore, a recycled industrial aluminum-containing material, red mud, fly ashes, slag, alumina, aluminum hydroxide, aluminum chloride and aluminum metal with an acid so as to obtain a leachate comprising said aluminum ions and ions from at least one metal; and optionally a solid residue;
optionally separating the leachate from the solid residue;
precipitating said aluminum ions from said leachate in the form of Al(OH) 3 at a pH of about 7 to about 10 in order to obtain a solid comprising said Al(OH) 3 and a liquid comprising said ions from said at least one metal;
separating said solid from said liquid;
converting said Al(OH) 3 into AlCl 3 by reacting Al(OH) 3 with HCl and precipitating said AlCl 3 ;
recovering said AlCl 3 ;
heating said AlCl 3 under conditions effective for converting AlCl 3 into Al 2 O 3 and optionally recovering gaseous HCl so-produced; and
converting said Al 2 O 3 into aluminum.