Process for producing modified conjugated diene-based polymer, modified conjugated diene-based polymer, and polymer composition
An object of the present invention is to provide a process for producing a modified conjugated diene-based polymer suitable for preparing a polymer composition excellent in the fuel cost saving effect. The present invention provides a process for producing a modified conjugated diene-based polymer, comprising reacting a conjugated diene-based polymer having a monomer unit based on a conjugated diene compound and a monomer unit based on a compound represented by the following formula (1), with an organometallic compound, and reacting the resulting reaction product with a hydrocarbyloxysilane compound: wherein R 11 , R 12 , R 13 , R 14 and R 15 each represent a hydrogen atom or an alkyl group, at least one of R 11 , R 12 , R 13 , R 14 and R 15 is an alkyl group, R 16 , R 17 and R 18 each represent a hydrogen atom or a hydrocarbyl group, R 19 represents a hydrocarbylene group, and k represents 0 or 1.
1. A process for producing a modified conjugated diene-based polymer, comprising reacting a conjugated diene-based polymer having a monomer unit based on a conjugated diene compound and a monomer unit based on a compound represented by the following formula (1) with an organometallic compound selected from a group consisting of an organolithium compound, an organosodium compound, and an organopotassium compound, and reacting the resulting reaction product with a hydrocarbyloxysilane compound:
wherein R 11 , R 12 , R 13 , R 14 and R 15 each represent a hydrogen atom or an alkyl group, at least one of R 11 , R 12 , R 13 , R 14 and R 15 is an alkyl group, R 16 , R 17 and R 18 each represent a hydrogen atom or a hydrocarbyl group, R 19 represents a hydrocarbylene group, and k represents 0 or 1,
wherein the organolithium compound comprises a hydrocarbyllithium compound or a hydrocarbylenedilithium compound,
the organosodium compound comprises sodium naphthalenide or sodium biphenylenide, and
the organopotassium compound comprises potassium naphthalenide, and
wherein the content of the monomer unit based on the compound represented by the formula (1) is 0.01% by weight or more and 0.5% by weight or less, letting the total amount of the monomer unit contained in the conjugated diene-based polymer be 100% by weight.
2. The process for producing a modified conjugated diene-based polymer according to claim 1 , wherein the hydrocarbyloxysilane compound is a hydrocarbyloxysilane compound having a nitrogen atom-containing group.
3. The process for producing a modified conjugated diene-based polymer according to claim 2 , wherein the hydrocarbyloxysilane compound is a hydrocarbyloxysilane compound having a substituted amino group.
4. The process for producing a modified conjugated diene-based polymer according to claim 1 , wherein the conjugated diene-based polymer has a nitrogen atom-containing group on at least one of polymer chain ends.
5. A modified conjugated diene-based polymer produced by the process as defined in claim 1 .
6. A polymer composition comprising the modified conjugated diene-based polymer as defined in claim 5 and a reinforcing agent, wherein the content of the reinforcing agent is 10 parts by weight to 150 parts by weight per the content of 100 parts by weight of the modified conjugated diene-based polymer.