Addition-curable silicone composition and a semiconductor device
The invention provides an addition-curable silicone composition which provides a cured product having good performance at a low temperature and excellent resistance to a temperature change, and to provide a semiconductor device having a high reliability, whose semiconductor element is encapsulated with the cured product. The invention provides an addition-curable silicone composition comprising (A) a branched organopolysiloxane having at least two alkenyl groups and represented by the formula (1) with a short branch consisting of 1 to 4 siloxane units, (B) an organohydrogenpolysiloxane having at least two hydrosilyl groups, in an amount such that a ratio of the number of the hydrosilyl groups in component (B) to the number of the alkenyl groups in component (A) is 0.4 to 4, and (C) a hydrosilylation catalyst in a catalytic amount. The invention also provides a semiconductor device provided with a cured product obtained by curing the condensation-curable silicone composition.
1. An addition-curable silicone composition comprising the following components (A) to (C):
(A) a branched organopolysiloxane having at least two alkenyl groups and represented by the following formula (1):
wherein R 1 is, independently of each other, a substituted or unsubstituted, saturated hydrocarbon group having 1 to 12 carbon atoms or a substituted or unsubstituted, aromatic hydrocarbon group having 6 to 12 carbon atoms, R 3 is, independently of each other, a substituted or unsubstituted, saturated hydrocarbon group having 1 to 12 carbon atoms, a substituted or unsubstituted, aromatic hydrocarbon group having 6 to 12 carbon atoms, or an alkenyl group having 2 to 10 carbon atoms, R 4 is, independently of each other, a substituted or unsubstituted, saturated hydrocarbon group having 1 to 6 carbon atoms or a substituted or unsubstituted, aromatic hydrocarbon group having 6 to 12 carbon atoms, R 5 is, independently of each other, an alkenyl group having 2 to 10 carbon atoms, k is an integer of from 0 to 3, provided that this organopolysiloxane has at least two alkenyl groups, x is an integer of from 0 to 3, a is an integer of from 1 to 100, and b is an integer of from 0 to 300, provided that a total of a and b is 1 to 400, wherein the parenthesized siloxane units may bond randomly or form a block unit;
(B) an organohydrogenpolysiloxane having at least two hydrosilyl groups, in an amount such that a ratio of the number of the hydrosilyl groups in component (B) to the number of the alkenyl groups in component (A) is 0.4 to 4, and
(C) a hydrosilylation catalyst in a catalytic amount.
2. The addition-curable silicone composition according to claim 1 , further comprising (D) an organopolysiloxane having a network structure and represented by the following formula (2):
(R 8 3 SiO 1/2 ) r (R 8 2 SiO 2/2 ) s (R 8 SiO 3/2 ) t (SiO 4/2 ) u (2)
wherein R 8 is, independently of each other, selected from the group consisting of a substituted or unsubstituted, saturated hydrocarbon group having 1 to 12 carbon atoms, a substituted or unsubstituted, aromatic hydrocarbon group having 6 to 12 carbon atoms, and an alkenyl group having 2 to 10 carbon atoms, provided that at least two of R 8 are an alkenyl group, r is an integer of from 0 to 100, s is an integer of from 0 to 300, t is an integer of from 0 to 200, and u is an integer of from 0 to 200, provided that a total of t and u is 1 to 400 and a total of r, s, t and u is 2 to 800, r, s, t, and u are such that this organopolysiloxane has at least two alkenyl groups,
in an amount of 5 to 900 parts by mass, relative to 100 parts by mass of component (A) and a ratio of the number of the hydrosilyl groups in component (B) to a total number of the alkenyl groups in components (A) and (D) is 0.4 to 4.
3. The addition-curable silicone composition according to claim 1 , wherein x is zero.
4. The addition-curable silicone composition according to claim 1 , wherein at least one of R 1 is an aromatic hydrocarbon group having 6 to 12 carbon atoms.
5. The addition-curable silicone composition according to claim 1 , wherein (A) the branched organopolysiloxane has a monovalent aromatic hydrocarbon group bonded to a silicon atom, in an amount of from 3% or more to 90% or less in number, based on a total number of the groups each bonded to a silicon atom.
6. The addition-curable silicone composition according to claim 1 , wherein component (B) is represented by the following formula (4):
(R 7 3 SiO 1/2 ) r′ (R 7 2 SiO 2/2 ) s′ (R 7 SiO 3/2 ) t′ (SiO 4/2 ) u′ (4)
wherein R 7 is, independently of each other, a hydrogen atom, a substituted or unsubstituted, saturated hydrocarbon group having 1 to 12 carbon atoms, or a substituted or unsubstituted, aromatic hydrocarbon group having 6 to 12 carbon atoms, at least two of R 7 are hydrogen atoms, r′ is an integer of from 0 to 100, s′ is an integer of from 0 to 300, t′ is an integer of from 0 to 200, and u′ is an integer of from 0 to 200, a total of r′, s′, t′ and u′ is 2 to 800, provided that r′, s′, t′, and u′ are such that this organohydrogenpolysiloxane has at least two hydrogen atoms.
7. A semiconductor device provided with a cured product obtained by curing the addition-curable silicone composition according to claim 1 .
8. The semiconductor device according to claim 7 , wherein the semiconductor device has a semiconductor element which is encapsulated with said cured product.
9. The semiconductor device according to claim 8 , wherein the semiconductor element is a light emitter.