Negative electrode for nonaqueous secondary battery, method for producing the same, and nonaqueous secondary battery
Provided is a negative electrode for a nonaqueous secondary battery which achieves both suppression of reductive decomposition of an electrolyte or an electrolytic solution and suppression of an increase in resistance. Also provided are a method for producing such a negative electrode and a nonaqueous secondary battery employing such a negative electrode. A polymer coating layer is formed so as to coat at least part of surfaces of negative electrode active material particles containing silicon oxide (SiO x ; 0.5≦x≦1.6). The polymer coating layer contains a cationic polymer having a positive zeta potential under neutral conditions. Since silicon oxide has a negative zeta potential, a thin uniform coating layer can be formed owing to Coulomb's force.
1. A negative electrode for a nonaqueous secondary battery, including a current collector and a negative electrode active material layer bonded to the current collector,
the negative electrode active material layer including negative electrode active material particles containing silicon oxide (SiO x ; 0.5≦x≦1.6), a bonding portion for bonding the negative electrode active material particles with each other and bonding the negative electrode active material particles with the current collector, and a polymer coating layer coating at least part of surfaces of at least the negative electrode active material particles, and
the polymer coating layer containing a cationic polymer having a positive zeta potential under neutral conditions,
wherein the polymer coating layer is formed by alternately depositing a layer of the cationic polymer and a layer of an anionic polymer having a negative zeta potential under neutral conditions, the cationic polymer layer being coated on a side of the negative electrode active material particles.
2. The negative electrode for a nonaqueous secondary battery according to claim 1 , wherein the polymer coating layer has a thickness of 10 nm or less.
3. The negative electrode for a nonaqueous secondary battery according to claim 1 , wherein the cationic polymer has a zeta potential of +20 mV or more.
4. The negative electrode for a nonaqueous secondary battery according to claim 1 , wherein the anionic polymer has a zeta potential of −10 mV or less.
5. A nonaqueous secondary battery including the negative electrode according to claim 1 .
6. The nonaqueous secondary battery according to claim 5 , having an electrolytic solution containing fluoroethylene carbonate.