Methods for coating metals on hydrophobic surfaces
View Patent ↗A method of plating a metal on a hydrophobic polymer, especially in the shape of small particles, involves: (a) contacting a surface of hydrophobic polymer substrate with a polycation such as poly(allylamine hydrochloride) to create a treated surface; (b) contacting the treated surface with a catalyst; and then (c) immersing the surface in a electroless metal plating bath to create a coating of metal on the surface. Metals include copper, silver, gold, nickel and cobalt. Catalysts are selected from compounds containing palladium, platinum, tin, copper, or nickel salts. Damaging surface treatments such as etching by plasma or acid are avoided.
1. A method for coating a metal on a hydrophobic surface of a substrate, comprising
(a) contacting the hydrophobic surface with a polycation to create a treated surface comprising the polycation;
(b) contacting the treated surface with a catalyst; and
(c) immersing the surface of step (b) in an electroless plating bath of the metal to create a coating of the metal on the surface.
2. The method according to claim 1 , wherein the substrate is in the form of particles having a dimension of 10 nm-1 cm.
3. The method according to claim 1 , wherein the metal comprises copper, silver, gold, nickel, or cobalt.
4. The method according to claim 3 , wherein the metal is copper or nickel.
5. The method according to claim 1 , wherein the substrate comprises a hydrophobic polymer selected from the group consisting of polyethylene, polypropylene, polystyrene and mixtures thereof.
6. The method according to claim 1 , wherein the catalyst comprises a compound of palladium, tin, copper, or nickel.
7. The method according to claim 1 , wherein the electroless plating bath comprises sodium borohydride.
8. The method according to claim 1 , wherein the polycation of step (a) is branched poly(ethyleneimine) or linear poly (ethyleneimine).
9. The method according to claim 1 , wherein the polycation is poly (diallyldimethylammonium chloride).
10. The method according to claim 1 , wherein the polycation of step (a) is poly(allylamine) hydrochloride (PAH).
11. The method according to claim 10 , wherein the substrate comprises a hydrophobic polymer selected from the group consisting of polyethylene, polypropylene, polystyrene and mixtures thereof.
12. The method according to claim 1 , wherein the catalyst comprises Pd.
13. The method according to claim 1 , wherein the catalyst comprises Ni or Cu.
14. The method according to claim 1 , wherein the substrate comprises particles of dimension 0.1 mm-1 cm.
15. The method according to claim 1 , wherein the substrate comprises particles of dimension 1-50 micrometers.
16. A method for forming a metal coating on a substrate comprising a hydrophobic polymer, comprising
(a) contacting the substrate with poly(allylamine hydrochloride) (PAH) to create a treated surface comprising the PAH;
(b) contacting the treated surface with a catalyst comprising Pd, Pt, Sn, Ni, or Cu; and
(c) immersing the surface in an electroless metal plating bath to create a coating of the metal on the surface,
wherein the meta is nickel or copper.
17. The method according to claim 16 , wherein the catalyst comprises Ni or Cu.
18. The method according to claim 16 , wherein the substrate is in the form of spherical particles.
19. The method according to claim 16 , wherein the method is carried out without etching of the substrate before contacting with PAH.