Open port sampling interface

1. A system for sampling a sample material, comprising:

a probe comprising an outer probe housing having an open end; a liquid supply conduit within the housing and having an outlet positioned to deliver liquid to the open end of the housing, the liquid supply conduit being connectable to a liquid supply for delivering liquid at a first volumetric flow rate to the open end of the housing, and a liquid exhaust conduit within the housing for removing liquid from the open end of the housing;

a liquid exhaust system in fluid connection with the liquid exhaust conduit for removing liquid from the liquid exhaust conduit at a second volumetric flow rate, the first volumetric flow rate exceeding the second volumetric flow rate, wherein during operation of the system liquid at the open end receives sample material, liquid containing sample material is drawn into and through the liquid exhaust conduit, and liquid overflows from the open end; and,

an overflow collection system for collecting the overflow liquid from the open end of the probe.

2. The system of claim 1 , wherein the liquid exhaust system comprises a connection for placing the liquid exhaust conduit in liquid communication with a chemical analysis device.

3. The system of claim 1 , wherein the collection system comprises a collection container surrounding the outer probe housing.

4. The system of claim 1 , wherein the liquid exhaust system comprises a connection for placing the liquid exhaust conduit in liquid communication with a chemical analysis device, and further comprising a processor, the processor receiving a signal from a chemical analysis device if a sample of interest is present in liquid from the liquid exhaust system, the processor then directing the collection of overflow liquid.

5. The system of claim 1 , wherein the collection system comprises a connection for placing overflow liquid collected by the collection system in liquid communication with a chemical analysis device.

6. The system of claim 1 , wherein the first volumetric flow rate is at least 5% greater than the second volumetric flow rate.

7. A method for sampling a sample material, comprising the steps of:

providing a probe comprising an outer probe housing having an open end, a liquid supply conduit within the housing and having an outlet positioned to deliver liquid to the open end of the housing, and an exhaust conduit within the housing for removing liquid from the open end of the housing;

providing a liquid exhaust system in fluid connection with the liquid exhaust conduit for removing liquid from the liquid exhaust conduit;

flowing liquid through the liquid supply conduit to deliver liquid at a first volumetric flow rate to the open end of the housing;

flowing liquid through the liquid exhaust system at a second volumetric flow rate, the first volumetric flow rate exceeding the second volumetric flow rate, wherein during operation of the probe liquid at the open end receives sample material, liquid containing the sample material is drawn into and through the liquid exhaust conduit, and liquid overflows from the open end; and,

further comprising the step of performing chemical analysis on liquid from the liquid exhaust system, and if an analyte of interest is detected in the chemical analysis, further comprising the step of collecting overflow liquid.

8. The method of claim 7 , further comprising the step of performing chemical analysis on liquid from the liquid exhaust system.

9. The method of claim 8 , wherein the chemical analysis is at least one selected from the group consisting of high performance liquid chromatography and mass spectrometry.

10. The method of claim 7 , wherein the probe comprises a liquid overflow collection system, and further comprising the step of collecting overflow liquid with the collection system.

11. The method of claim 10 , further comprising the step of directing overflow liquid from the collection system to a chemical analysis device.

12. The method of claim 7 , wherein the first volumetric flow rate is at least 5% greater than the second volumetric flow rate.

13. A probe for sampling a sample material, comprising:

an outer probe housing having an inner wall and an open end;

a liquid supply conduit within the housing and having an outlet positioned to deliver liquid to the open end of the housing;

an exhaust conduit within the housing for removing liquid from the open end of the housing;

the liquid supply conduit being connectable to a liquid supply for delivering liquid at a first volumetric flow rate to the open end of the housing, the liquid exhaust conduit being connectable to a liquid exhaust system for removing liquid from the liquid exhaust conduit at a second volumetric flow rate, the first volumetric flow rate exceeding the second volumetric flow rate, wherein during operation of the probe liquid at the open end receives sample material, liquid containing sample material is drawn into and through the liquid exhaust conduit, and liquid overflows from the open end; and,

further comprising a collection system for collecting the overflow liquid from the open end of the probe during operation of the probe.

14. The probe of claim 13 , wherein the collection system comprises a container surrounding the outer probe housing.