Polyester resin composition and molded article containing this resin composition
An object is to improve both slow crystallization and brittleness that are drawbacks of polyhydroxyalkanoates, so that processability in mold processing, such as injection molding, is improved, processing speed is increased, and ductility is imparted to a resulting molded article. Provided is an aliphatic polyester resin composition including a polyhydroxyalkanoate (A), an ethylene-vinyl acetate copolymer resin (B), and pentaerythritol (C), wherein the ethylene-vinyl acetate copolymer resin (B) has a vinyl acetate content of 65 to 95 wt %, and the polyhydroxyalkanoate (A) and the ethylene-vinyl acetate copolymer resin (B) are compatible.
1. An aliphatic polyester resin composition comprising:
a polyhydroxyalkanoate (A),
an ethylene-vinyl acetate copolymer resin (B), and
pentaerythritol (C),
wherein the polyhydroxyalkanoate (A) is one or more selected from poly(3-hydroxybutyrate-co-3-hydroxyvalerate-co-3-hydroxyhexanoate), poly(3-hydroxybutyrate-co-3-hydroxyhexanoate), and poly(3-hydroxybutyrate-co-4-hydroxybutyrate), the ethylene-vinyl acetate copolymer resin (B) has a vinyl acetate content of 65 to 95 wt %, and the polyhydroxyalkanoate (A) and the ethylene-vinyl acetate copolymer resin (B) are compatible and present in a weight ratio, (A)/(B) of 80/20 to 55/45,
and wherein the ratio of 3-hydroxybutyrate/comonomer in said poly(3-hydroxybutyrate-co-3-hydroxyvalerate-co-3-hydroxyhexanoate), poly(3-hydroxybutyrate-co-3-hydroxyhexanoate), and poly(3-hydroxybutyrate-co-4-hydroxybutyrate) is 97/3 to 80/20 mol %/mol %.
2. The aliphatic polyester resin composition according to claim 1 , wherein the weight ratio of the polyhydroxyalkanoate (A) to the ethylene-vinyl acetate copolymer resin (B) is 60/40 to 55/45.
3. The aliphatic polyester resin composition according to claim 1 , wherein an amount of the pentaerythritol (C) present in said composition is 0.05 to 20 parts by weight with respect to 100 parts by weight of a total amount of the polyhydroxyalkanoate (A) and the ethylene-vinyl acetate copolymer resin (B) present in said composition.
4. The aliphatic polyester resin composition according to claim 1 , wherein the composition comprises poly(3-hydroxybutyrate-co-3-hydroxyvalerate-co-3-hydroxyhexanoate).
5. A polyester resin molded article obtained by molding the aliphatic polyester resin composition according to claim 1 .
6. The aliphatic polyester resin composition according to claim 1 , wherein the composition comprises poly(3-hydroxybutyrate-co-3-hydroxyhexanoate).
7. The aliphatic polyester resin composition according to claim 1 , wherein the composition comprises poly(3-hydroxybutyrate-co-4-hydroxybutyrate).
8. The aliphatic polyester resin composition according to claim 1 , wherein the ratio of 3-hydroxybutyrate/comonomer in said poly(3-hydroxybutyrate-co-3-hydroxyvalerate-co-3-hydroxyhexanoate), poly(3-hydroxybutyrate-co-3-hydroxyhexanoate), and poly(3-hydroxybutyrate-co-4-hydroxybutyrate) is 95/5 to 85/15 mol %/mol %.
9. The aliphatic polyester resin composition according to claim 1 , wherein the weight-average molecular weight of the polyhydroxyalkanoate (A) is 200,000 to 2,500,000.
10. The aliphatic polyester resin composition according to claim 1 , wherein the weight-average molecular weight of the polyhydroxyalkanoate (A) is 300,000 to 1,000,000.
11. The aliphatic polyester resin composition according to claim 1 , wherein the amount of pentaerythritol (C) present in said composition is 0.5-10 parts by weight with respect to 100 parts by weight of the total amount of the polyhydroxyalkanoate (A) and the ethylene-vinyl acetate copolymer resin (B) present in said composition.
12. The aliphatic polyester resin composition according to claim 1 , wherein:
a weight ratio of the polyhydroxyalkanoate (A) to the ethylene-vinyl acetate copolymer resin (B) is 60/40 to 55/45;
the weight-average molecular weight of the polyhydroxyalkanoate (A) is 200,000 to 2,500,000; and
the amount of pentaerythritol (C) present in said composition is 0.05-20 parts by weight with respect to 100 parts by weight of the total amount of the polyhydroxyalkanoate (A) and the ethylene-vinyl acetate copolymer resin (B) present in said composition.
13. A polyester resin molded article obtained by molding the aliphatic polyester resin composition according to claim 12 .
14. The aliphatic polyester resin composition according to claim 1 , wherein the amount of said pentaerythritol (C) present in said composition is sufficient to promote the crystallization of said polyhydroxyalkanoate (A).