Flotation process for recovering feldspar from a feldspar ore
A flotation process for recovering feldspar from a feldspar containing feed material is disclosed. The process includes forming an aqueous suspension of a feldspar containing feed material, in the absence of hydrofluoric acid, wherein the suspension includes from 0.004 to 0.3% wt. of a flotation reagent including: (a) one or more amines, containing at least one aliphatic hydrocarbon chain, linear or branched, saturated or unsaturated, including 8 to 50 carbon atoms, or a salt thereof; and (b) one or more primary, secondary or tertiary alcohols, containing at least one aliphatic hydrocarbon chain, linear or branched, saturated or unsaturated, including 8 to 50 carbon atoms; the ratio of (a) to (b) ranging from 500:1 to 1:40 by weight. The process further includes agitating the obtained suspension to produce a feldspar containing fraction, and separating the feldspar containing fraction.
1. A flotation process for recovering feldspar, the process comprising:
(i) forming an aqueous suspension of a feed material comprising feldspar, in the absence of hydrofluoric acid, wherein the suspension has a pH ranging from 1.3 to 3.0, and wherein the suspension comprises from 0.004% wt. to 0.3% wt. of a flotation reagent comprising:
(a) one or more cationic amines, containing at least one aliphatic hydrocarbon chain, linear or branched, saturated or unsaturated, comprising 8 to 50 carbon atoms, or a salt thereof; and
(b) at least one alcohol chosen from C 12 -C 32 2-alkyl-1-alkanols, C 10 -C 25 iso-alcohols, and mixtures thereof;
wherein the ratio of (a) to (b) ranges from 500:1 to 1:40 by weight;
(ii) agitating the suspension to produce a feldspar containing fraction; and
(iii) separating the feldspar containing fraction.
2. The flotation process according to claim 1 , wherein the ratio of (a) to (b) ranges from 200:1 to 1:20 by weight.
3. The flotation process according to claim 1 , wherein the ratio of (a) to (b) ranges from 35:1 to 1:5 by weight.
4. The flotation process according to claim 1 , wherein in step (i), the pH of the aqueous suspension ranges from 1.6 to 1.9.
5. The flotation process according to claim 1 , wherein step (i) includes adding sulfuric acid or hydrochloric acid to the suspension.
6. The flotation process according to claim 1 , wherein step (i) includes adding from 0.1 kg to 1.5 kg of acid per ton of feed material.
7. The flotation process according to claim 1 , wherein the feed material has a solids concentration ranging from 20% wt. to 75% wt.
8. The flotation process according to claim 1 , wherein component (a) is an amine of formula (I):
wherein R 1 is an alkyl group, linear or branched, saturated or unsaturated, containing 8 to 50 carbon atoms, and
R 2 and R 3 are independently selected from H and an alkyl group, the alkyl group being linear or branched, saturated or unsaturated, and containing 1 to 5 carbon atoms.
9. The flotation process according to claim 8 , wherein R 1 contains 10 to 30 carbon atoms.
10. The flotation process according to claim 9 , wherein each of R 2 and R 3 contains 1 to 3 carbon atoms.
11. The flotation process according to claim 8 , wherein R 1 contains 12 to 25 carbon atoms.
12. The flotation process according to claim 11 , wherein each of R 2 and R 3 contains 1 to 3 carbon atoms.
13. The flotation process according to claim 8 , wherein each of R 2 and R 3 contains 1 to 3 carbon atoms.
14. The flotation process according to claim 1 , wherein in step (i), the amount of component (a) in the aqueous suspension ranges from 0.003% wt. to 0.15% wt., and from 0.05 kg to 2 kg of acid is added per ton of feed material.
15. The flotation process according to claim 1 , wherein the amount of component (b) in the aqueous suspension ranges from 0.0005% wt. to 0.15% wt., and the consumption of component (b) ranges from 0.01 kg/ton to 2 kg/ton of feed material.
16. The flotation process according to claim 1 , wherein the feed material has an average particle size ranging from 1 micron to 800 microns.
17. The flotation process according to claim 1 , wherein the feed material has an average particle size ranging from 50 microns to 400 microns.
18. The flotation process according to claim 1 , wherein in the concentration of the feldspar containing feed material ranges from 5% wt. to 50% wt. during process step (ii).
19. The flotation process according to claim 1 , wherein the concentration of the feldspar containing feed material ranges from 25% wt. to 30% wt. during process step (ii).
20. The flotation process according to claim 1 , wherein the pH of the suspension ranges from 1.6 to 5.5 during process step (ii).
21. The flotation process according to claim 1 , wherein the pH of the suspension ranges from 2.5 to 4.0 during process step (ii).
22. The flotation process according to claim 1 , wherein the feed material is obtained from a feldspar ore.
23. A flotation process for recovering feldspar, the process comprising:
combining at least one N-alkyl cationic amine with an aqueous suspension of a feed material comprising feldspar, in the absence of hydrofluoric acid, to form a first mixture, wherein the mixture has a pH ranging from 1.3 to 3.0;
adding to the first mixture at least one non-ionic branched primary alcohol comprising 10 to 50 carbon atoms to form a second mixture, wherein the weight ratio of the at least one N-alkyl cationic amine to the at least one non-ionic branched primary alcohol ranges from 500:1 to 1:40;
agitating the second mixture to produce a fraction comprising feldspar; and
separating the fraction from a remainder of the second mixture, wherein the at least one non-ionic branched primary alcohol comprises a C 12 -C 32 2-alkyl-1-alkanol, a C 10 -C 25 iso-alcohol, or a mixture thereof.