IP Library Granted Patent US 9,683,204
Granted Patent B2
US 9,683,204 · App. 14/406,298 · Granted Jun 20, 2017

Visually contrasting aesthetic particles having increased water solubility, particularly useful for combination with powdered or granular compositions

Inventors: Richard Lock (Chester, GB); Michael Pickstock (Northwich, GB)
Assignee: AMCOL INTERNATIONAL CORPORATION
C11D3/40C11D1/04C11D3/126C11D3/2079C11D7/02C11D7/265C11D9/18C11D9/444C11D17/06C11D17/065
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Quick Facts
Patent No.
US 9,683,204
App. No.
14/406,298
Granted
Jun 20, 2017
Kind
B2
Abstract

The present invention is directed to visually contrasting aesthetic particles having increased water solubility, particularly useful for combination with granular laundry detergent composition.

Claims (27)

1. Visually contrasting aesthetic particles, each particle comprising a mixture of:

about 60 wt % to about 70 wt % sodium oleate;

about 10 wt % to about 20 wt % sodium montmorillonite clay;

about 10 wt % to about 20 wt % calcium montmorillonite clay, wherein the particles leave less than 5% by weight residue when subjected to a dissolution test, the dissolution test comprising:

(i) adding 3.5 g of laundry detergent immediately followed by 1 g of aesthetic particles to a vessel containing 1000 ml medium hardness water at a temperature of 15° C. while stirring at 200 rpm,

(ii) after the aesthetic particles completely dissolve or 15 minutes of stirring, which ever is first, pouring the wash liquid and any undissolved material onto a 150 μm sieve and rinsing with de-ionized water,

(iii) transferring the liquid and any undissolved material to a Buchner funnel and filtering through a dried and pre-weighed Whatman Type 4 filter paper, and

(iv) drying the filter paper at 105° C. and weighing to determine the weight percent of residue.

2. The aesthetic particles of claim 1 , wherein the particles comprise about 60 wt. % sodium oleate; about 20 wt. % of sodium montmorillonite clay and about 20 wt. % calcium montmorillonite clay, dry basis.

3. The aesthetic particles of claim 1 , wherein the particles comprise about 70 wt. % sodium oleate; about 15 wt. % sodium montmorillonite clay; and about 15 wt. % calcium montmorillonite clay, wherein weight percentages are based on the total dry weight of the particles.

4. A method of manufacturing the visually contrasting aesthetic particles according to claim 1 comprising mixing together a composition comprising about 60 wt. % to about 70 wt. % sodium oleate with about 10 wt. % to about 20 wt. % sodium montmorillonite clay and about 10 wt. % to about 20 wt. % calcium montmorillonite clay; extruding the composition through a die opening to form the composition into an extrudate, and subdividing the extrudate into individual particles.

5. The method of claim 4 , further including a dye or pigment in the composition in an amount of about 0.01 wt. % to 1.0 wt. % to form particles having a color that is distinguishable from detergent product combined therewith.

6. The method of claim 4 , wherein the composition further comprises about 0.01 wt. % to about 0.5 wt. % colorant material, dry basis.

7. An extrudable composition for shaping into visually contrasting aesthetic particles, said particles providing a visual cue when combined with a product in an amount less than about 10 wt. % of said product, said composition having a color that visually contrasts with a color of said product, said contrasting aesthetic particles comprising a mixture of:

a colorant,

about 60 wt % to

about 70 wt % sodium oleate,

about 10 wt % to about 20 wt % sodium montmorillonite clay, and

about 10 wt % to about 20 wt % calcium montmorillonite clay, wherein the visually contrasting aesthetic particles leave less than about 15% residue when subjected to a dissolution test, the dissolution test comprising:

(i) adding 3.5 g of laundry detergent immediately followed by 1 g of aesthetic particles to a vessel containing 1000 ml medium hardness water at a temperature of 15° C. while stirring at 200 rpm,

(ii) after, the first of, the aesthetic particles completely dissolving or 15 minutes of stirring, pouring the wash liquid and any undissolved material onto a 150 μm sieve and rinsing with de-ionized water,

(iii) transferring the liquid and any undissolved material to a Buchner funnel and filtering through a dried and pre-weighed Whatman Type 4 filter paper, and

(iv) drying the filter paper at 105° C. and weighing to determine the weight percent of residue.

8. A composition as claimed in claim 7 , wherein the visually contrasting aesthetic particles are of regular shape.

9. A composition as claimed in claim 7 , wherein the visually contrasting aesthetic particles are of uniform size and shape.

10. A composition as claimed in claim 7 , wherein the visually contrasting aesthetic particles are of brightly colored material having a distinct contrast from a white or light-colored product combined therewith.

11. A composition as claimed in claim 7 , wherein the visually contrasting aesthetic particles are of highly reflective material.

Assignments (2)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 20, 2016
From: LOCK, RICHARD; PICKSTOCK, MICHAEL
To: AMCOL INTERNATIONAL CORPORATION
Reel/Frame 039196/0979 →
SUPPLEMENTAL PATENT SECURITY AGREEMENT Recorded Feb 9, 2016
From: AMCOL INTERNATIONAL CORPORATION
To: JPMORGAN CHASE BANK, N.A., AS ADMINISTRATIVE AGENT
Reel/Frame 037753/0105 →
Continuity (3)
Provisional Application 61676265 · Jul 26, 2012
Provisional Application 61657141 · Jun 8, 2012
Related Publication 20150126428A1 · May 7, 2015