Electrophoretic particles and processes for the production thereof
Polymer shells similar to those described in U.S. Pat. No. 6,822,782 can be formed on pigment particles by (a) physi-sorping a reagent comprising polymerizable groups on to the pigment particles by treating the particle with a reagent having a polymerizable or polymerization-initiating group, such that the reagent will not desorb from the particle surface when the particle is placed in a hydrocarbon medium; or (b) treating pigment particles bearing nucleophilic groups with a reagent having a polymerizable or polymerization-initiating group, and an electrophilic group, thus attaching the polymerizable or polymerization-initiating groups to the particle surface. The zeta potential of the pigment particles can be varied by a process similar to (b) but using a reagent which does not have a polymerizable or polymerization-initiating group.
1. A process for treatment of pigment particles comprising:
providing pigment particles having surfaces bearing nucleophilic groups; and
contracting the pigment particles with a reagent having a polymerizable or polymerization-initiating group, and also comprising at least one electrophilic group under conditions which cause the electrophilic groups on the reagent to react with the nucleophilic groups on the particle surfaces, thus attaching the polymerizable or polymerization-initiating groups to the particle surface.
2. A process according to claim 1 further comprising reacting the pigment particle with the polymerizable or polymerization-initiating groups thereon with at least one monomer or oligomer under conditions effective to cause reaction between the polymerizable or polymerization-initiating group on the particle and the at least one monomer or oligomer, thereby causing the formation of polymer on the particle.
3. A process according to claim 1 wherein the pigment is an organic pigment containing a nitrogenous ring.
4. A process according to claim 3 wherein the pigment is a quinacridone dye.
5. A process according to claim 1 , wherein the reagent is an acid halide.
6. A process according to claim 5 , wherein the reagent is 4-vinylbenzyl chloride.
7. A process according to claim 5 , wherein the reagent is methacryloyl chloride.
8. A process according to claim 1 , wherein the reagent is 2-isocyanatoethyl methacrylate.