Metal-organic framework catalysts for selective cleavage of aryl-ether bonds
The present invention relates to methods of employing a metal-organic framework (MOF) as a catalyst for cleaving chemical bonds. In particular instances, the MOF results in selective bond cleavage that results in hydrogenolyzis. Furthermore, the MOF catalyst can be reused in multiple cycles. Such MOF-based catalysts can be useful, e.g., to convert biomass components.
1. A method of cleaving a bond in a test compound comprising:
exposing the test compound to a metal-organic framework in the presence of a hydrogen source, wherein the test compound comprises a carbon-oxygen bond,
thereby cleaving the carbon-oxygen bond.
2. The method of claim 1 , wherein the carbon-oxygen bond is an ether bond or an aryl ether bond.
3. The method of claim 1 , wherein the metal-organic framework comprises a dopant.
4. The method of claim 3 , wherein the dopant comprises a nanoparticle.
5. The method of claim 3 , wherein the dopant comprises a second metal selected from the group consisting of titanium, nickel, rhodium, ruthenium, rhenium, iridium, copper, iron, platinum, palladium, and a combination thereof.
6. The method of claim 1 , wherein the metal-organic framework comprises a plurality of nodes, an organic linker connecting at least two of the plurality of nodes, and an optional dopant comprising a second metal; and optionally wherein at least one of the plurality of nodes comprises one or more open metal sites.
7. The method of claim 6 , wherein at least one of the plurality of nodes comprises a metal atom or a cluster thereof including a plurality of metal atoms.
8. The method of claim 7 , wherein the metal atom comprises a metal ion.
9. The method of claim 6 , wherein at least one node comprises magnesium or an ionic form thereof, the dopant comprises nickel and/or titanium or an ionic form thereof, and the organic linker comprises an optionally substituted arylene.
10. The method of claim 1 , wherein the metal-organic framework comprises a pore having a diameter that is at least two times larger than a dimension of the test compound.
11. The method of claim 1 , wherein the test compound is an organic compound, an organic polymer, or a biomass component.
12. The method of claim 1 , wherein the test compound comprises lignin, cellulose, hemicellulose, and/or a fragment thereof.
13. The method of claim 1 , wherein cleaving the carbon-oxygen bond forms two or more resultant cleavage products; and wherein each of the test compound and cleavage products is, independently, an organic moiety.
14. The method of claim 1 , wherein the exposing step is further conducted in the presence of an ionic liquid and/or without the presence of a base.
15. The method of claim 1 , further comprising:
separating the metal-organic framework from the reacted test compound; and
reusing the metal-organic framework for a further reaction with another test compound.
16. A method comprising:
providing a biomass component; and
exposing the biomass component to a metal-organic framework in the presence of a hydrogen source, wherein the biomass component comprises a carbon-oxygen bond,
thereby cleaving the carbon-oxygen bond present in the biomass component.
17. The method of claim 16 , wherein carbon-oxygen bond is an ether bond or an aryl ether bond.
18. The method of claim 16 , wherein the metal-organic framework comprises a plurality of nodes, an organic linker connecting at least two of the plurality of nodes, and an optional dopant comprising a second metal; and optionally wherein at least one of the plurality of nodes comprises an open metal site.
19. The method of claim 16 , wherein the exposing step is further conducted in the presence of an ionic liquid.