Electrolyte for batteries with regenerative solid electrolyte interface
An energy storage device comprising: an anode; and a solute-containing electrolyte composition wherein the solute concentration in the electrolyte composition is sufficiently high to form a regenerative solid electrolyte interface layer on a surface of the anode only during charging of the energy storage device, wherein the regenerative layer comprises at least one solute or solvated solute from the electrolyte composition.
1. A battery device comprising:
an anode comprising graphite;
a cathode comprising sulfur; and
an electrolyte composition selected from:
(i) a solute comprising lithium bis(trifluoromethanesulphonyl) imide and a solvent comprising 1,3-dioxolane, wherein the solute concentration in the electrolyte composition is at least 3M, as measured by moles of solute divided by the volume of the solvent without considering the volume change of the electrolyte composition after dissolving the solute;
(ii) a solute comprising lithium bis(trifluoromethanesulphonyl) imide and a solvent comprising 1,2-dimethoxyethane, wherein the solute concentration in the electrolyte composition is at least 7M, as measured by moles of solute divided by the volume of the solvent without considering the volume change of the electrolyte composition after dissolving the solute; or
(iii) a solute selected from lithium bis(trifluoromethanesulphonyl) imide, LiPF 6 , or LiClO 4 , and a solvent comprising propylene carbonate, wherein the solute concentration in the electrolyte composition is at least 5M, as measured by moles of solute divided by the volume of the solvent without considering the volume change of the electrolyte composition after dissolving the solute.
2. A method comprising:
cycling the battery device of claim 1 ; and
forming a regenerative layer on a surface of the anode only during charging of the battery device, wherein the regenerative layer comprises at least one solute from the electrolyte composition.
3. The battery device of claim 1 , wherein the electrolyte composition is the electrolyte composition (i).
4. The battery device of claim 1 , wherein the electrolyte composition is the electrolyte composition (ii).
5. The battery device of claim 1 , wherein the electrolyte composition is the electrolyte composition (iii).
6. The battery device of claim 3 , wherein the solvent consists of 1,3-dioxolane.
7. The battery device of claim 1 , wherein the device undergoes charge/discharge cycles without significant decline in specific capacity over at least 100 cycles.
8. The battery device of claim 1 , wherein the regenerative solid electrolyte interface layer does not include any products from decomposition of the electrolyte solute.
9. The battery device of claim 1 , wherein the electrolyte composition does not include ethylene carbonate.