Metal-insulator-metal structure and method for forming the same

1. A method for manufacturing a semiconductor structure, comprising:

forming a bottom electrode layer over a substrate by a physical vapor deposition process;

forming a first passivation layer over the bottom electrode layer by a first atomic layer deposition process;

forming a dielectric layer over the first passivation layer by a second atomic layer deposition process;

forming a second passivation layer over the dielectric layer by a third atomic layer deposition process;

forming a top electrode layer over the second passivation layer;

patterning the top electrode layer and the second passivation layer to have a first width; and

patterning the dielectric layer, the first passivation layer, and the bottom electrode layer to have a second width, wherein the second width is greater than the first width,

wherein the bottom electrode layer and the first passivation layer are made of a same material, but the bottom electrode layer is a crystalline layer and the first passivation layer is an amorphous layer.

2. The method for manufacturing a semiconductor structure as claimed in claim 1 , wherein the top electrode layer is formed by a physical vapor deposition (PVD) process.

3. The method for manufacturing a semiconductor structure as claimed in claim 1 , wherein the first atomic layer deposition process, the second atomic layer deposition process, and the third atomic layer deposition process, which are respectively used to form the first passivation layer, the dielectric layer, and the second passivation layer, are performed in the same apparatus.

4. The method for manufacturing a semiconductor structure as claimed in claim 1 , wherein the first atomic layer deposition process comprises using H 2 /N 2 plasma.

5. The method for manufacturing a semiconductor structure as claimed in claim 1 , wherein the second passivation layer is an amorphous layer, and the top electrode layer is a crystalline layer.

6. The method for manufacturing a semiconductor structure as claimed in claim 1 , wherein the first passivation layer is made of TiN or TaN.

7. The method for manufacturing a semiconductor structure as claimed in claim 1 , wherein the first passivation layer has a thickness in a range from about 15 Å to about 50 Å.

8. A method for manufacturing a metal-insulator-metal structure, comprising:

forming a bottom electrode layer over a substrate;

forming a first passivation layer over the bottom electrode layer in a first chamber of an apparatus;

forming a dielectric layer over the first passivation layer in a second chamber of the apparatus;

forming a second passivation layer over the dielectric layer in the first chamber of the apparatus; and

forming a top electrode layer over the second passivation layer,

wherein the bottom electrode layer and the first passivation layer are made of a same material with different molecular arrangements.

9. The method for manufacturing a metal-insulator-metal structure as claimed in claim 8 , wherein the bottom electrode layer and the top electrode layer are formed by physical vapor deposition (PVD) processes.

10. The method for manufacturing a metal-insulator-metal structure as claimed in claim 8 , wherein H 2 /N 2 plasma is applied into the first chamber of an atomic layer deposition apparatus when the first passivation layer and the second passivation layer are formed.

11. The method for manufacturing a metal-insulator-metal structure as claimed in claim 8 , wherein the first passivation layer and the second passivation layer are amorphous layers, and the top electrode layer and the bottom electrode layer are crystalline layers.

12. The method for manufacturing a metal-insulator-metal structure as claimed in claim 8 , wherein the first passivation layer is made of TiN or TaN.

13. The method for manufacturing a metal-insulator-metal structure as claimed in claim 8 , wherein the first passivation layer has a thickness in a range from about 15 Å to about 50 Å.

14. A metal-insulator-metal structure, comprising:

a bottom electrode layer formed over a substrate;

a first passivation layer formed over the bottom electrode layer;

a dielectric layer formed over the first passivation layer;

a second passivation layer formed over the dielectric layer; and

a top electrode layer formed over the second passivation layer,

wherein the first passivation layer and the second passivation layer are amorphous layers, and the bottom electrode layer and the first passivation layer are made of a same material with different molecular arrangements,

wherein the top electrode layer and the second passivation layer have a first width, and

wherein the dielectric layer, the first passivation layer, and the bottom electrode layer have a second width which is greater than the first width.

15. The metal-insulator-metal structure as claimed in claim 14 , wherein the first passivation layer is made of TaN or TiN.

16. The metal-insulator-metal structure as claimed in claim 14 , wherein the first passivation layer has a thickness in a range from about 15 Å to about 50 Å.

17. The metal-insulator-metal structure as claimed in claim 14 , wherein the top electrode layer and the bottom electrode layer are crystalline layers.

18. The method for manufacturing a metal-insulator-metal structure as claimed in claim 1 , wherein the bottom electrode layer has a rough top surface and the first passivation layer has a smooth top surface.

19. The method for manufacturing a metal-insulator-metal structure as claimed in claim 8 , further comprising:

patterning the top electrode layer and the second passivation layer to have a first width; and

patterning the dielectric layer, the first passivation layer, and the bottom electrode layer to have a second width,

wherein the second width is greater than the first width.

20. The metal-insulator-metal structure as claimed in claim 14 , wherein a roughness of the bottom electrode layer is greater than a roughness of the first passivation layer.