Material and applications therefor
A gel film or an isolated gel film comprising sheets of graphene or chemically converted graphene at least partially separated by a dispersion medium, such as water, and arranged in a substantially planar manner to form an electrically conductive matrix.
1. A gel film, comprising sheets of graphene or chemically converted graphene at least partially separated by a dispersion medium and arranged in a substantially planar manner to form an electrically conductive matrix, wherein the gel film does not comprise a ceramic or an inorganic oxide particle.
2. The gel film according to claim 1 , wherein the gel is an organogel.
3. The gel film according to claim 1 , wherein the gel is a hydrogel.
4. The gel film according claim 3 , consisting essentially of graphene or chemically converted graphene and water as the dispersion medium.
5. The gel film according to claim 1 , wherein an available surface area of graphene or chemically converted graphene is at least about 1000 m 2 /mg.
6. An article comprising the gel film according to claim 1 , wherein the article is selected from the group consisting of:
an electrode for an energy storage or conversion device selected from the group consisting of a supercapacitor, a battery, a fuel cell, a solar cell and an actuator;
an electrode for an electrochemical sensor or for a resistive sensor;
a filtration membrane for nanoparticle or molecule separation;
a controlled drug release and/or delivery drug formulation comprising the gel film as a carrier;
a conductive tissue scaffold for cell growth;
a catalyst comprising the gel film as a support;
an adsorbent for water purification and/or separation; and
a materials component.
7. A hybrid gel film comprising the gel film according to claim 1 , which is suitable as a scaffold.
8. The hybrid gel film according to claim 7 , wherein the hybrid gel film comprises a material selected from the group consisting of an organic molecule, a polymer, a biomolecule, an inorganic nanoparticle, a metal nanoparticle, and an inorganic oxide particle.
9. A device, comprising the gel film according to claim 1 .
10. The device according to claim 9 , which is selected from the group consisting of a biomedical device, an electrode, a battery, a separation device, a sensor; and an actuator.
11. The device of claim 10 , which is an electrode which is a superconductor.
12. An isolated gel film, comprising sheets of graphene or chemically converted graphene at least partially separated by a dispersion medium and arranged in a substantially planar manner to form an electrically conductive matrix, wherein the gel film does not comprise a ceramic or an inorganic oxide particle.
13. A method of producing a gel film, comprising:
contacting a surface with a dispersion medium comprising sheets of graphene or chemically converted graphene dispersed therein;
removing some of the dispersion medium from the surface and allowing the sheets to self-assemble to form a gel film on the surface,
wherein the sheets of graphene or chemically converted graphene are at least partially separated by the dispersion medium and are arranged in a substantially planar manner to form an electrically conductive matrix and wherein the gel film does not comprise a ceramic or an inorganic oxide particle.
14. The method according to claim 13 , further comprising:
applying a conductive layer onto the surface before the contacting of the surface with the dispersion medium comprising sheets of graphene or chemically converted graphene dispersed therein.
15. The method according to claim 13 , further comprising:
separating the gel film from the surface.
16. The method according to claim 13 , wherein the dispersion medium comprises one or more additives.
17. The method according to claim 15 , further comprising:
adding one or more additives to the gel film after the gel film has been separated from the surface.
18. The method according to claim 13 , wherein:
the surface is a filter; and
the dispersion medium is removed from the surface by passage through the filter.
19. The method according to claim 18 , wherein filtration occurs under vacuum.
20. The method according to claim 13 , wherein the dispersion medium is water.
21. The method according to claim 13 , wherein the dispersion medium is an organic liquid.
22. The method according to claim 13 , wherein the dispersion medium comprises a drug.
23. The method according to claim 13 , further comprising increasing a temperature of the dispersion medium, wherein the temperature is increased to control a resultant inter-sheet spacing in the gel film that forms on the surface.
24. The method according to claim 23 , wherein the temperature is increased such that the gel film permits passage of particles having a first average diameter but does not permit passage of particles having a diameter larger than the first average diameter.
25. The method according to claim 23 , wherein the temperature is increased to a range of about 90 to 150° C.
26. The method according to claim 23 , wherein temperature of the dispersion medium is increased before the step of contacting the surface.
27. The method according to claim 26 , wherein the dispersion medium is cooled before the step of contacting the surface.
28. A filtration membrane produced by the method according to claim 23 .