IP Library Granted Patent US 9,758,656
Granted Patent B2
US 9,758,656 · App. 14/915,452 · Granted Sep 12, 2017

Soft touch compositions and articles thereof

Inventors: Jana Hrachova (Geleen, NL); Franciscus Elisabeth Jacobus Essers (Geleen, NL)
Assignee: SABIC GLOBAL TECHNOLOGIES B.V.
C08L23/12C08L2201/08C08L2205/02C08L2205/03C08L2205/035C08L2207/02
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Quick Facts
Patent No.
US 9,758,656
App. No.
14/915,452
Granted
Sep 12, 2017
Kind
B2
Abstract

A soft touch composition comprises, based on the total weight of the composition, 50 to 88 wt % of a polymer comprising, based on the total weight of the polymer, 44 to 52 wt % of a polypropylene homopolymer, 3 to 30 wt % of an ethylene-propylene copolymer, and 22 to 52 wt % of an ethylene-C 4 to C 8 alpha olefin copolymer, and 10 to 40 wt % of glass fibers.

Claims (39)

1. A soft touch composition comprising, based on the total weight of the composition,

10 to 40 wt % of glass fibers; and

50 to 88 wt % of a polymer comprising, based on the total weight of the polymer,

44 to 52 wt % of a polypropylene homopolymer,

3 to 30 wt % of an ethylene-propylene copolymer, and

22 to 52 wt % of an ethylene-C 4 to C 8 alpha olefin copolymer

wherein the polypropylene homopolymer has a melt flow index of 5 to 150 g/10 min measured at 230° C. under 2.16 kg force according to ISO 1133 and/or a cold xylene soluble fraction of the ethylene-propylene copolymer has an intrinsic viscosity of 2 to 8 dl/g measured in decalin at 135° C. and/or the ethylene-C 4 to C 8 alpha olefin copolymer has a density of 850 to 880 kg/m 3 and a melt flow index of 0.5 to 35 g/10 min measured at 190° C. under 2.16 kg force according to ISO 1133.

2. The composition of claim 1 , wherein a cold xylene soluble fraction of the ethylene-propylene copolymer has an intrinsic viscosity of 3 to 8 dl/g measured in decalin at 135° C.

3. The composition of claim 1 , wherein the ethylene-C 4 to C 8 alpha olefin copolymer is polymerized from ethylene and at least one of 1-butene, 1-hexene, and 1-octene.

4. The composition of claim 1 , wherein the glass fibers have a filament diameter of 10 to 20 micrometers.

5. The composition of claim 1 , further comprising a modified polypropylene, wherein the modified polypropylene is a polypropylene grafted with a carboxylic acid or salts thereof, an anhydride, an ester, or a combination comprising at least one of the foregoing.

6. The composition of claim 5 , wherein the modified polypropylene is a homopolypropylene grafted with maleic anhydride.

7. The composition of claim 1 , further comprising 0.1 to 5 wt % of a colorant.

8. The composition of claim 1 , further comprising a polysiloxane, wherein the polysiloxane comprises an ultra high molecular weight polysiloxane with a kinematic viscosity of greater than 10×10 6 centistokes as determined in accordance with ASTM D445.

9. The composition of claim 8 , wherein the polysiloxane is present in an amount of 0.2 to 10 wt %.

10. The composition of claim 1 , wherein the composition further comprises 0.1 to 2 wt % of a thermal stabilizer, a UV stabilizer, a visible light stabilizer, an antioxidant, or a combination comprising one or more of the foregoing.

11. An article made from the composition of claim 1 .

12. A soft touch composition comprising, based on the total weight of the composition,

10 to 40 wt % of glass fibers; and

50 to 88 wt % of a polymer comprising, based on the total weight of the polymer,

44 to 52 wt % of a polypropylene homopolymer,

3 to 30 wt % of an ethylene-propylene copolymer, and

22 to 52 wt % of an ethylene-C 4 to C 8 alpha olefin copolymer, and

further comprising a homopolypropylene grafted with maleic anhydride; wherein a functional group derived from maleic anhydride is present in an amount of greater than or equal to 0.5 wt %, based on the total weight of the homopolypropylene;

wherein the polypropylene homopolymer has a melt flow index of 5 to 150 g/10 min measured at 230° C. under 2.16 kg force according to ISO 1133 and/or a cold xylene soluble fraction of the ethylene-propylene copolymer has an intrinsic viscosity of 2 to 8 dl/g measured in decalin at 135° C. and/or the ethylene-C 4 to C 8 alpha olefin copolymer has a density of 850 to 880 kg/m 3 and a melt flow index of 0.5 to 35 g/10 min measured at 190° C. under 2.16 kg force according to ISO 1133.

13. The composition of claim 12 , wherein the homopolypropylene is present in an amount of 0.1 to 4 wt %, based on the total weight of the composition.

14. A soft touch composition comprising, based on the total weight of the composition,

10 to 40 wt % of glass fibers; and

50 to 88 wt % of a polymer comprising, based on the total weight of the polymer,

44 to 52 wt % of a polypropylene homopolymer,

3 to 30 wt % of an ethylene-propylene copolymer, and

22 to 52 wt % of an ethylene-C 4 to C 8 alpha olefin copolymer, and

further comprising a silicone particle having the formula (I)

R x SiO 2-(x/2)   (I)

wherein x is a positive number greater than or equal to 1, and each R is independently an aliphatic hydrocarbon group, an aromatic hydrocarbon, or an unsaturated group;

wherein the polypropylene homopolymer has a melt flow index of 5 to 150 g/10 min measured at 230° C. under 2.16 kg force according to ISO 1133 and/or a cold xylene soluble fraction of the ethylene-propylene copolymer has an intrinsic viscosity of 2 to 8 dl/g measured in decalin at 135° C. and/or the ethylene-C 4 to C 8 alpha olefin copolymer has a density of 850 to 880 kg/m 3 and a melt flow index of 0.5 to 35 g/10 min measured at 190° C. under 2.16 kg force according to ISO 1133.

15. The composition of claim 14 , wherein the silicone particle comprises methylsilsequioxane.

16. The composition of claim 14 , wherein the silicone particle has a mean particle diameter of 1.8 to 10.5 micrometers.

17. The composition of claim 14 , wherein the silicone particle is present in an amount of 1 to 5 wt %, based on the total weight of the composition.

Assignments (2)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 27, 2016
From: HRACHOVA, JANA; ESSERS, FRANCISCUS ELISABETH JACOBUS
To: SABIC INNOVATIVE PLASTICS IP B.V.
Reel/Frame 039269/0022 →
CHANGE OF NAME Recorded Jul 27, 2016
From: SABIC INNOVATIVE PLASTICS IP B.V.
To: SABIC GLOBAL TECHNOLOGIES B.V.
Reel/Frame 039491/0101 →
Priority Claims (1)
EP 13183137 · Sep 5, 2013 · regional
Continuity (2)
Provisional Application 61871016 · Aug 28, 2013
Related Publication 20160208084A1 · Jul 21, 2016